Thermochemical measurement of the ligand field splitting energies for hexaammine complexes of Mn(II), Fe(II), and Zn(II)

• Main Authors: Badri, M., Jamieson, J. W. S.
• Format: Article
• Language: English
• Published: N R C Research Press 1977
• Online Access: http://psasir.upm.edu.my/id/eprint/33953/1/25.%2033953%20thermochemical%20measurement%20of%20the%20ligand.pdf; http://psasir.upm.edu.my/id/eprint/33953/; http://www.nrcresearchpress.com/doi/abs/10.1139/v77-494#.VTaUYCGeDGd

Various lower ammines and high-energy modifications of lower ammines of the sulphates of Mn(II), Fe(II), and Zn(II) have been prepared and their heats of solution have been mea- sured. For each of these ammine systems, the maximum difference in heat of solution, ex- pressed in kcal(mol of heptaammin...