Ligand field splitting energies of the hexaamminecobalt(II) ion and the hexaamminenickel(II) ion measured by a calorimetric method

• Main Authors: Muhammmad, Badri, Jamieson, J. W. S.
• Format: Article
• Language: English
• Published: N R C Research Press 1970
• Online Access: http://psasir.upm.edu.my/id/eprint/33881/1/15.%2033881%20ligand%20field%20splitting.pdf; http://psasir.upm.edu.my/id/eprint/33881/; http://www.nrcresearchpress.com/doi/abs/10.1139/v70-364#.VTZyDCGeDGc

Various normal lower ammines and high-energy modifications of the lower ammines of cobalt(II) sulfate and nickel(II) sulfate have been prepared and the heats of solution in dilute ammonia have been measured for both types. For each of these ammine systems the maximum difference in heat of solution,...