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Thermochemical measurement of the ligand field splitting energies for hexaammine complexes of Mn(II), Fe(II), and Zn(II)

Various lower ammines and high-energy modifications of lower ammines of the sulphates of Mn(II), Fe(II), and Zn(II) have been prepared and their heats of solution have been mea- sured. For each of these ammine systems, the maximum difference in heat of solution, ex- pressed in kcal(mol of heptaammin...

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Main Authors: Badri, M., Jamieson, J. W. S.
Format: Article
Language:English
Published: N R C Research Press 1977
Online Access:http://psasir.upm.edu.my/id/eprint/33953/1/25.%2033953%20thermochemical%20measurement%20of%20the%20ligand.pdf
http://psasir.upm.edu.my/id/eprint/33953/
http://www.nrcresearchpress.com/doi/abs/10.1139/v77-494#.VTaUYCGeDGd
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spelling my.upm.eprints.339532015-04-21T08:22:01Z http://psasir.upm.edu.my/id/eprint/33953/ Thermochemical measurement of the ligand field splitting energies for hexaammine complexes of Mn(II), Fe(II), and Zn(II) Badri, M. Jamieson, J. W. S. Various lower ammines and high-energy modifications of lower ammines of the sulphates of Mn(II), Fe(II), and Zn(II) have been prepared and their heats of solution have been mea- sured. For each of these ammine systems, the maximum difference in heat of solution, ex- pressed in kcal(mol of heptaammine, has been found to be of the right order of magnitude to be regarded as the ligand field splitting energy for the hexaammine complex of the metal ion. N R C Research Press 1977 Article PeerReviewed application/pdf en http://psasir.upm.edu.my/id/eprint/33953/1/25.%2033953%20thermochemical%20measurement%20of%20the%20ligand.pdf Badri, M. and Jamieson, J. W. S. (1977) Thermochemical measurement of the ligand field splitting energies for hexaammine complexes of Mn(II), Fe(II), and Zn(II). Canadian Journal of Chemistry, 55 (20). pp. 3530-3535. ISSN 0008-4042; ESSN: 1480-3291 http://www.nrcresearchpress.com/doi/abs/10.1139/v77-494#.VTaUYCGeDGd
institution Universiti Putra Malaysia
building UPM Library
collection Institutional Repository
continent Asia
country Malaysia
content_provider Universiti Putra Malaysia
content_source UPM Institutional Repository
url_provider http://psasir.upm.edu.my/
language English
description Various lower ammines and high-energy modifications of lower ammines of the sulphates of Mn(II), Fe(II), and Zn(II) have been prepared and their heats of solution have been mea- sured. For each of these ammine systems, the maximum difference in heat of solution, ex- pressed in kcal(mol of heptaammine, has been found to be of the right order of magnitude to be regarded as the ligand field splitting energy for the hexaammine complex of the metal ion.
format Article
author Badri, M.
Jamieson, J. W. S.
spellingShingle Badri, M.
Jamieson, J. W. S.
Thermochemical measurement of the ligand field splitting energies for hexaammine complexes of Mn(II), Fe(II), and Zn(II)
author_facet Badri, M.
Jamieson, J. W. S.
author_sort Badri, M.
title Thermochemical measurement of the ligand field splitting energies for hexaammine complexes of Mn(II), Fe(II), and Zn(II)
title_short Thermochemical measurement of the ligand field splitting energies for hexaammine complexes of Mn(II), Fe(II), and Zn(II)
title_full Thermochemical measurement of the ligand field splitting energies for hexaammine complexes of Mn(II), Fe(II), and Zn(II)
title_fullStr Thermochemical measurement of the ligand field splitting energies for hexaammine complexes of Mn(II), Fe(II), and Zn(II)
title_full_unstemmed Thermochemical measurement of the ligand field splitting energies for hexaammine complexes of Mn(II), Fe(II), and Zn(II)
title_sort thermochemical measurement of the ligand field splitting energies for hexaammine complexes of mn(ii), fe(ii), and zn(ii)
publisher N R C Research Press
publishDate 1977
url http://psasir.upm.edu.my/id/eprint/33953/1/25.%2033953%20thermochemical%20measurement%20of%20the%20ligand.pdf
http://psasir.upm.edu.my/id/eprint/33953/
http://www.nrcresearchpress.com/doi/abs/10.1139/v77-494#.VTaUYCGeDGd
_version_ 1643831015601340416
score 13.159267

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