Kinetics and mechanism of the cleavage of Phthalic Anhydride in Glacial Acetic Acid Solvent containing Aniline
Apparent second-order rate constants (k(n)(app)) for the nucleophilic reaction of aniline (Ani) with phthalic anhydride (PAn) vary from 6.30 to 7.56 M(-1) s(-1) with the increase of temperature from 30 to 50 degrees C in pure glacial acetic acid (AcOH). However, the values of pseudo-first-order rate...
Saved in:
Main Authors: | Ariffin, Azhar, Khan, M.N., Damit, E.F. |
---|---|
Format: | Article |
Published: |
2008
|
Subjects: | |
Online Access: | http://eprints.um.edu.my/8055/ http://pubs.acs.org/doi/pdfplus/10.1021/jo8011072 |
Tags: |
Add Tag
No Tags, Be the first to tag this record!
|
Similar Items
-
Effects of pure Acoh and mixed AcOH-CS (CS = CH3CN And THF) solvents on the rate of cleavage of Phthalic Anhydride (PAn)
by: Ariffin, Azhar, et al.
Published: (2012) -
Unexpected rate retardation in the formation of phthalic anhydride from N-Methylphthalamic Acid in acidic H2O-CH3CN medium
by: Ariffin, Azhar, et al.
Published: (2005) -
Lipase-catalyzed esterification of betulinic acid using phthalic anhydride in organic solvent media: study of reaction parameters
by: Moghaddam, Mansour Ghaffari, et al.
Published: (2010) -
Electrical Behavior of Polyurethane Derived from Polyols Synthesized with Glycerol, Phthalic Anhydride, and Oleic Acid
by: Velayutham, T.S., et al.
Published: (2011) -
Synthesis and Characterization of Polyurethane Coatings derived from Polyols Synthesized with Glycerol, Phthalic Anhydride and Oleic Acid
by: Velayutham, T.S., et al.
Published: (2009)