Kinetics and mechanism of the cleavage of Phthalic Anhydride in Glacial Acetic Acid Solvent containing Aniline

Apparent second-order rate constants (k(n)(app)) for the nucleophilic reaction of aniline (Ani) with phthalic anhydride (PAn) vary from 6.30 to 7.56 M(-1) s(-1) with the increase of temperature from 30 to 50 degrees C in pure glacial acetic acid (AcOH). However, the values of pseudo-first-order rate...

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Bibliographic Details
Main Authors: Ariffin, Azhar, Khan, M.N., Damit, E.F.
Format: Article
Published: 2008
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Online Access:http://eprints.um.edu.my/8055/
http://pubs.acs.org/doi/pdfplus/10.1021/jo8011072
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