Kinetics And Mechanism Of The Cleavage Of N-Methoxyphthalimide (NMPT) In The Presence Of Buffers Of Tris (Hydroxymethyl)Amino-Methane (Tris) And 1,4-Diazabicyclo 2.2.2 Octane (DABCO)
The magnitude of hydroxide ion-catalyzed second-order rate constant (k(OH)) for hydrolysis of N-methoxyphthalimide (NMPT) supports the conclusion that the rate law for pH-independent hydrolysis of N-hydroxyphthalimide (NHPTH) is rate = k(OH)[HO-][SH], where SH represents nonionized NHPTH. The second...
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Format: | Article |
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2003
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Online Access: | http://eprints.um.edu.my/8039/ http://download.springer.com/static/pdf/638/art%253A10.1023%252FA%253A1022590606020.pdf?auth66=1362627082_995652ddd594452e2551c21fe860d5c6&ext=.pdf |
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