Kinetic evidence for the formation of monocationic N,N'-Disubstituted Phthalamide in tertiary Amine-Catalyzed hydrolysis of N-Substituted Phthalimides
A kinetic study on the aqueous cleavage of N-(2-methoxyphenyl)phthalimide (1) and N-(2-hydroxyphenyl)-phthalimide (2), under the buffers of N-methylmorphohne, reveals the equilibrium presence of monocationic amide (Ctam) formed due to nucleophilic reactions of N-methylmorpholine with 1 and 2. Pseudo...
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| Main Authors: | , , |
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| Format: | Article |
| Published: |
2007
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| Subjects: | |
| Online Access: | http://eprints.um.edu.my/8052/ http://pubs.acs.org/doi/pdfplus/10.1021/jo701295n |
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