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Kinetic coupled with UV spectral evidenc for near-irreversible nonionic micellar binding of n-benzylphthalimide under the typical reaction conditions: an observation against a major assumption of the pseudophase micellar model

Pseudo-first-order rate constants (k(obs)) for alkaline hydrolysis of N-benzylphthalimide (1) show a nonlinear decrease with the increase in [C,,,E,,]T (total concentration of Brij 58, m = 16, n = 20 and Brij 56, nt = 16, n = 10) at constant [CH3CN] and [NaOH]. These nonionic micellar effects, withi...

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書誌詳細
主要な著者:	Ariffin, Azhar, Khan, M.N., Cheong, M.Y.
フォーマット:	論文
出版事項:	2007
主題:	QD Chemistry
オンライン･アクセス:	http://eprints.um.edu.my/8050/ http://pubs.acs.org/doi/pdfplus/10.1021/jp073980j
タグ:	タグ追加タグなし, このレコードへの初めてのタグを付けませんか!

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