Kinetic coupled with UV spectral evidenc for near-irreversible nonionic micellar binding of n-benzylphthalimide under the typical reaction conditions: an observation against a major assumption of the pseudophase micellar model
Pseudo-first-order rate constants (k(obs)) for alkaline hydrolysis of N-benzylphthalimide (1) show a nonlinear decrease with the increase in [C,,,E,,]T (total concentration of Brij 58, m = 16, n = 20 and Brij 56, nt = 16, n = 10) at constant [CH3CN] and [NaOH]. These nonionic micellar effects, withi...
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| Main Authors: | , , |
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| Format: | Article |
| Published: |
2007
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| Subjects: | |
| Online Access: | http://eprints.um.edu.my/8050/ http://pubs.acs.org/doi/pdfplus/10.1021/jp073980j |
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