A comparative analysis of Pseudophase Ion-Exchange (PIE) model and Berezin Pseudophase (BPP) model: analysis of kinetic data for Ionic Micellar-Mediated Semi-Ionic Bimolecular Reaction

• Main Authors: Ariffin, Azhar, Khan, M.N., Cheong, M.Y.
• Format: Article
• Published: 2007
• Subjects: QD Chemistry
• Online Access: http://eprints.um.edu.my/8051/; http://koreascience.or.kr/article/ArticleFullRecord.jsp?cn=JCGMCS_2007_v28n7_1135

Pseudo-first-order rate constants (k(obs)) for the reaction of N-benzylphthalimide (NBPT) with HO- have been determined at 2.0 x 10(-4) M NBPT, 1.0 x 10(-3) and 2.0 x 10(-3) M NaOH as well as varying concentrations of cetyltrimethylammonium bromide ([CTABr](T) = 0.0-1.7 x 10(-1) M). The effects of [...