Kinetic coupled with UV spectral evidenc for near-irreversible nonionic micellar binding of n-benzylphthalimide under the typical reaction conditions: an observation against a major assumption of the pseudophase micellar model

• Main Authors: Ariffin, Azhar, Khan, M.N., Cheong, M.Y.
• 格式: Article
• 出版: 2007
• 主題: QD Chemistry
• 在線閱讀: http://eprints.um.edu.my/8050/; http://pubs.acs.org/doi/pdfplus/10.1021/jp073980j

Pseudo-first-order rate constants (k(obs)) for alkaline hydrolysis of N-benzylphthalimide (1) show a nonlinear decrease with the increase in [C,,,E,,]T (total concentration of Brij 58, m = 16, n = 20 and Brij 56, nt = 16, n = 10) at constant [CH3CN] and [NaOH]. These nonionic micellar effects, withi...