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trans-Bis(1H-indole-3-carbaldehyde thio­semicarbazonato-κ2 N 1,S)nickel(II)

The Ni atom in the centrosymmetric title compound, [Ni(C10H9N4S)2], is N,S-chelated by the deprotonated Schiff bases in a square-planar geometry. The –CH=N—N=C(S)—NH2 frament is planar. Adjacent mol­ecules are linked by hydrogen bonds between the indolyl –NH (donor) site and the double-bond =N– (acc...

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Main Authors: Rizal, Mohd Razali, Ali, Hapipah Mohd, Ng, Seik Weng
Format: Article
Language:English
Published: International Union of Crystallography 2008
Subjects:
QD Chemistry
Online Access:http://eprints.um.edu.my/5439/1/Rizal-2008-trans-Bis%281H-indole-.pdf
http://eprints.um.edu.my/5439/
https://doi.org/10.1107/S1600536808014293
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spelling my.um.eprints.54392020-12-11T07:33:56Z http://eprints.um.edu.my/5439/ trans-Bis(1H-indole-3-carbaldehyde thio­semicarbazonato-κ2 N 1,S)nickel(II) Rizal, Mohd Razali Ali, Hapipah Mohd Ng, Seik Weng QD Chemistry The Ni atom in the centrosymmetric title compound, [Ni(C10H9N4S)2], is N,S-chelated by the deprotonated Schiff bases in a square-planar geometry. The –CH=N—N=C(S)—NH2 frament is planar. Adjacent mol­ecules are linked by hydrogen bonds between the indolyl –NH (donor) site and the double-bond =N– (acceptor) site of an adjacent mol­ecule, forming a layer motif. International Union of Crystallography 2008 Article PeerReviewed application/pdf en http://eprints.um.edu.my/5439/1/Rizal-2008-trans-Bis%281H-indole-.pdf Rizal, Mohd Razali and Ali, Hapipah Mohd and Ng, Seik Weng (2008) trans-Bis(1H-indole-3-carbaldehyde thio­semicarbazonato-κ2 N 1,S)nickel(II). Acta Crystallographica Section E: Structure Reports Online, 64 (Pt 6). m824. ISSN 1600-5368 https://doi.org/10.1107/S1600536808014293 doi:10.1107/s1600536808014293
institution Universiti Malaya
building UM Library
collection Institutional Repository
continent Asia
country Malaysia
content_provider Universiti Malaya
content_source UM Research Repository
url_provider http://eprints.um.edu.my/
language English
topic QD Chemistry
spellingShingle QD Chemistry
Rizal, Mohd Razali
Ali, Hapipah Mohd
Ng, Seik Weng
trans-Bis(1H-indole-3-carbaldehyde thio­semicarbazonato-κ2 N 1,S)nickel(II)
description The Ni atom in the centrosymmetric title compound, [Ni(C10H9N4S)2], is N,S-chelated by the deprotonated Schiff bases in a square-planar geometry. The –CH=N—N=C(S)—NH2 frament is planar. Adjacent mol­ecules are linked by hydrogen bonds between the indolyl –NH (donor) site and the double-bond =N– (acceptor) site of an adjacent mol­ecule, forming a layer motif.
format Article
author Rizal, Mohd Razali
Ali, Hapipah Mohd
Ng, Seik Weng
author_facet Rizal, Mohd Razali
Ali, Hapipah Mohd
Ng, Seik Weng
author_sort Rizal, Mohd Razali
title trans-Bis(1H-indole-3-carbaldehyde thio­semicarbazonato-κ2 N 1,S)nickel(II)
title_short trans-Bis(1H-indole-3-carbaldehyde thio­semicarbazonato-κ2 N 1,S)nickel(II)
title_full trans-Bis(1H-indole-3-carbaldehyde thio­semicarbazonato-κ2 N 1,S)nickel(II)
title_fullStr trans-Bis(1H-indole-3-carbaldehyde thio­semicarbazonato-κ2 N 1,S)nickel(II)
title_full_unstemmed trans-Bis(1H-indole-3-carbaldehyde thio­semicarbazonato-κ2 N 1,S)nickel(II)
title_sort trans-bis(1h-indole-3-carbaldehyde thio­semicarbazonato-κ2 n 1,s)nickel(ii)
publisher International Union of Crystallography
publishDate 2008
url http://eprints.um.edu.my/5439/1/Rizal-2008-trans-Bis%281H-indole-.pdf
http://eprints.um.edu.my/5439/
https://doi.org/10.1107/S1600536808014293
_version_ 1687394115128393728
score 13.164666

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