Bis[1,5-bis­(1H-indol-3-ylmethyl­ene)thio­carbazonato-κ2 N,S]nickel(II) dimethyl sulfoxide disolvate

• Main Authors: Rizal, Mohd Razali, Ali, Hapipah Mohd, Ng, Seik Weng
• Format: Article
• Language: English
• Published: International Union of Crystallography 2008
• Subjects: QD Chemistry
• Online Access: http://eprints.um.edu.my/5440/1/Rizal-2008-Bis_1%2C5-bis%281H-indol.pdf; http://eprints.um.edu.my/5440/; https://doi.org/10.1107/S1600536808011975

The Ni atom in the crystal structure of the centrosymmetric title compound, [Ni(C19H15N6S)2]·2C2H6OS, is N,S-chelated by the deprotonated Schiff bases in a square-planar geometry. The –CH=N—N=C(S)—NH—N=CH– frament is planar. The two indolyl –NH (donor) sites inter­act with dimethyl sulfoxide mol­ecu...