trans-Bis(1H-indole-3-carbaldehyde thio­semicarbazonato-κ2 N 1,S)nickel(II)

• Main Authors: Rizal, Mohd Razali, Ali, Hapipah Mohd, Ng, Seik Weng
• Format: Article
• Language: English
• Published: International Union of Crystallography 2008
• Subjects: QD Chemistry
• Online Access: http://eprints.um.edu.my/5439/1/Rizal-2008-trans-Bis%281H-indole-.pdf; http://eprints.um.edu.my/5439/; https://doi.org/10.1107/S1600536808014293

The Ni atom in the centrosymmetric title compound, [Ni(C10H9N4S)2], is N,S-chelated by the deprotonated Schiff bases in a square-planar geometry. The –CH=N—N=C(S)—NH2 frament is planar. Adjacent mol­ecules are linked by hydrogen bonds between the indolyl –NH (donor) site and the double-bond =N– (acc...