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Cost and energy saving process for the laboratory-scale production of chloroform-d

Deuterochloroform (CDCl3), a commonly deuterated solvent in research and undergraduate laboratories and widely employed for nuclear magnetic resonance analyses, could be prepared using a more sustainable and efficient catalytic process. The synthesis includes a one-pot reaction of hexachloroacetone...

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Main Authors: Zaharani, Lia, Johan, Mohd Rafie, Khaligh, Nader Ghaffari
Format: Article
Published: American Chemical Society 2022
Subjects:
QD Chemistry
Online Access:http://eprints.um.edu.my/40382/
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spelling my.um.eprints.403822023-11-22T07:14:59Z http://eprints.um.edu.my/40382/ Cost and energy saving process for the laboratory-scale production of chloroform-d Zaharani, Lia Johan, Mohd Rafie Khaligh, Nader Ghaffari QD Chemistry Deuterochloroform (CDCl3), a commonly deuterated solvent in research and undergraduate laboratories and widely employed for nuclear magnetic resonance analyses, could be prepared using a more sustainable and efficient catalytic process. The synthesis includes a one-pot reaction of hexachloroacetone with deuterium oxide (D2O) in the presence of poly(N-vinylimidazole). The catalyst is more sustainable, highly recyclable, highly chemical and thermally stable, soluble in D2O, and high in efficiency. American Chemical Society 2022-10-21 Article PeerReviewed Zaharani, Lia and Johan, Mohd Rafie and Khaligh, Nader Ghaffari (2022) Cost and energy saving process for the laboratory-scale production of chloroform-d. Organic Process Research and Development, 26 (11). pp. 3126-3129. ISSN 1083-6160, DOI https://doi.org/10.1021/acs.oprd.2c00260 <https://doi.org/10.1021/acs.oprd.2c00260>. 10.1021/acs.oprd.2c00260
institution Universiti Malaya
building UM Library
collection Institutional Repository
continent Asia
country Malaysia
content_provider Universiti Malaya
content_source UM Research Repository
url_provider http://eprints.um.edu.my/
topic QD Chemistry
spellingShingle QD Chemistry
Zaharani, Lia
Johan, Mohd Rafie
Khaligh, Nader Ghaffari
Cost and energy saving process for the laboratory-scale production of chloroform-d
description Deuterochloroform (CDCl3), a commonly deuterated solvent in research and undergraduate laboratories and widely employed for nuclear magnetic resonance analyses, could be prepared using a more sustainable and efficient catalytic process. The synthesis includes a one-pot reaction of hexachloroacetone with deuterium oxide (D2O) in the presence of poly(N-vinylimidazole). The catalyst is more sustainable, highly recyclable, highly chemical and thermally stable, soluble in D2O, and high in efficiency.
format Article
author Zaharani, Lia
Johan, Mohd Rafie
Khaligh, Nader Ghaffari
author_facet Zaharani, Lia
Johan, Mohd Rafie
Khaligh, Nader Ghaffari
author_sort Zaharani, Lia
title Cost and energy saving process for the laboratory-scale production of chloroform-d
title_short Cost and energy saving process for the laboratory-scale production of chloroform-d
title_full Cost and energy saving process for the laboratory-scale production of chloroform-d
title_fullStr Cost and energy saving process for the laboratory-scale production of chloroform-d
title_full_unstemmed Cost and energy saving process for the laboratory-scale production of chloroform-d
title_sort cost and energy saving process for the laboratory-scale production of chloroform-d
publisher American Chemical Society
publishDate 2022
url http://eprints.um.edu.my/40382/
_version_ 1783876706009874432
score 13.214268

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