Cost and energy saving process for the laboratory-scale production of chloroform-d
Deuterochloroform (CDCl3), a commonly deuterated solvent in research and undergraduate laboratories and widely employed for nuclear magnetic resonance analyses, could be prepared using a more sustainable and efficient catalytic process. The synthesis includes a one-pot reaction of hexachloroacetone...
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| Main Authors: | , , |
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| Format: | Article |
| Published: |
American Chemical Society
2022
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| Subjects: | |
| Online Access: | http://eprints.um.edu.my/40382/ |
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| Summary: | Deuterochloroform (CDCl3), a commonly deuterated solvent in research and undergraduate laboratories and widely employed for nuclear magnetic resonance analyses, could be prepared using a more sustainable and efficient catalytic process. The synthesis includes a one-pot reaction of hexachloroacetone with deuterium oxide (D2O) in the presence of poly(N-vinylimidazole). The catalyst is more sustainable, highly recyclable, highly chemical and thermally stable, soluble in D2O, and high in efficiency. |
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