Mono- and di-anionic coordination modes of arylazosalicylates in their bis(η5-cyclopentadienyl)titanium(IV) complexes: Syntheses and crystal structures

• Main Authors: Basu Baul, Tushar S., Manne, Rajesh, Tiekink, Edward R. T. *
• Format: Article
• Language: English
• Published: Elsevier 2019
• Subjects: QD Chemistry
• Online Access: http://eprints.sunway.edu.my/920/1/Tiekink%20Inorganica%20Chimca%20Acta%202018%20final%20accepted.pdf; http://eprints.sunway.edu.my/920/; http://doi.org/10.1016/j.ica.2018.09.076

The bis(η5-cyclopentadienyl)titanium(IV) complexes of 5-[(E)-2-(aryl)-1-diazenyl]-2-hydroxybenzoic acids (H2LXASA) where the aryl group is an X-substituted phenyl ring such that X = CH, COEt, CMe, CF, CCl, CBr and N have been synthesised. Two types of titanium(IV) compounds viz. (i) [Ti(η5-C5H5)2(O2...