Crystalline bis(η5-cyclopentadienyl)bis(benzoato/carboxylato)titanium(IV) precursordirected route to functional titanium dioxide nanomaterials

• Main Authors: Basu Baul, Tushar S., Manne, Rajesh, Tiekink, Edward R. T. *
• Format: Article
• Language: English
• Published: Taylor & Francis 2018
• Subjects: QD Chemistry
• Online Access: http://eprints.sunway.edu.my/1004/1/Tiekink%20Crystalline%20bis%20JCC%202018%2071%203458%20%28acc%20%20doc%29.pdf; http://eprints.sunway.edu.my/1004/; https://www.tandfonline.com/doi/abs/10.1080/00958972.2018.1528355?journalCode=gcoo20; https://doi.org/10.1080/00958972.2018.1528355

Five titanocene(IV) carboxylates of the general formula Cp2Ti(O2CR)2 viz., [Ti(η5-C5H5)2(O2CC6H5-4-CH3)2] (1), [Ti(η5 -C5H5)2(O2CC4H3-2-O)2] (2), [Ti(η5-C5H5)2(O2CC4H3-3-O)2] (3), [Ti(η5-C5H5)2(O2CC(CH3)3)2] (4) and [Ti(η5-C5H5)2(O2C(CH)C(CH3)3)2] (5) have been synthesized. All the titanocene(IV) c...