Distinct coordination geometries in bis[N,N-bis(2-methoxyethyl)dithiocarbamato-κ2S,S′]diphenyltin(IV) and bis[N-(2-methoxyethyl)-N-methyldithiocarbamato-κ2S,S′]diphenyltin(IV): crystal structures and Hirshfeld surface analysis

• Main Authors: Rapidah Mohamad,, Normah Awang,, Jotani, Mukesh M., Tiekink, Edward R. T. *
• Format: Article
• Language: English
• Published: International Union of Crystallography 2016
• Subjects: QD Chemistry
• Online Access: http://eprints.sunway.edu.my/645/1/Acta%20E_RC%202016%2072%201130.pdf; http://eprints.sunway.edu.my/645/; http://dx.doi.org/10.1107/S2056989016011385

The crystal and mol­ecular structures of two di­phenyl­tin bis­(di­thio­carbamate)s, [Sn(C6H5)2(C5H10NOS2)2], (I), and [Sn(C6H5)2(C7H14NO2S2)2], (II), are described. In (I), in which the metal atom lies on a twofold rotation axis, the di­thio­carbamate ligand coordinates with approximately equal Sn-...