Crystal structures and Hirshfeld surface analyses of bis[N,N-bis(2-methoxyethyl)dithiocarbamato-κ2 S,S′]di-n-butyltin(IV) and [N-(2-methoxyethyl)-N-methyldithiocarbamato-κ2 S,S′]triphenyltin(IV)

• Main Authors: Mohamad Rapidah,, Awang Normah,, Kamaludin Nurul Farahana,, Jotani, Mukesh M., Tiekink, Edward R. T. *
• Format: Article
• Language: English
• Published: 2018
• Subjects: QD Chemistry
• Online Access: http://eprints.sunway.edu.my/753/1/Tiekink%20Crystal%20structures%20and%20Hirshfeld.pdf; http://eprints.sunway.edu.my/753/; http://doi.org/10.1107/S2056989018001901

The crystal and molecular structures of the two title organotin dithiocarbamate compounds, [Sn(C4H9)2(C7H14NO2S2)2], (I), and [Sn(C6H5)3(C5H10NOS2)], (II), are described. Both structures feature asymmetrically bound dithiocarbamate ligands leading to a skew-trapezoidal bipyramidal geometry for the m...