Crystal structures and Hirshfeld surface analyses of bis[N,N-bis(2-methoxyethyl)dithiocarbamato-κ2 S,S′]di-n-butyltin(IV) and [N-(2-methoxyethyl)-N-methyldithiocarbamato-κ2 S,S′]triphenyltin(IV)
The crystal and molecular structures of the two title organotin dithiocarbamate compounds, [Sn(C4H9)2(C7H14NO2S2)2], (I), and [Sn(C6H5)3(C5H10NOS2)], (II), are described. Both structures feature asymmetrically bound dithiocarbamate ligands leading to a skew-trapezoidal bipyramidal geometry for the m...
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my.sunway.eprints.7532020-10-07T09:20:29Z http://eprints.sunway.edu.my/753/ Crystal structures and Hirshfeld surface analyses of bis[N,N-bis(2-methoxyethyl)dithiocarbamato-κ2 S,S′]di-n-butyltin(IV) and [N-(2-methoxyethyl)-N-methyldithiocarbamato-κ2 S,S′]triphenyltin(IV) Mohamad Rapidah, Awang Normah, Kamaludin Nurul Farahana, Jotani, Mukesh M. Tiekink, Edward R. T. * QD Chemistry The crystal and molecular structures of the two title organotin dithiocarbamate compounds, [Sn(C4H9)2(C7H14NO2S2)2], (I), and [Sn(C6H5)3(C5H10NOS2)], (II), are described. Both structures feature asymmetrically bound dithiocarbamate ligands leading to a skew-trapezoidal bipyramidal geometry for the metal atom in (I) and a distorted tetrahedral geometry in (II). The complete molecule of (I) is generated by a crystallographic twofold axis (Sn site symmetry 2). In the crystal of (I), molecules self-assemble into a supramolecular array parallel to (101) via methylene-C—H...O(methoxy) interactions. In the crystal of (II), supramolecular dimers are formed via pairs of weak phenyl-C—H...π(phenyl) contacts. In each of (I) and (II), the specified assemblies connect into a threedimensional architecture without directional interactions between them. Hirshfeld surface analyses confirm the importance of H...H contacts in the molecular packing of each of (I) and (II), and in the case of (I), highlight the importance of short methoxy-H...H(butyl) contacts between layers. 2018 Article PeerReviewed text en http://eprints.sunway.edu.my/753/1/Tiekink%20Crystal%20structures%20and%20Hirshfeld.pdf Mohamad Rapidah, and Awang Normah, and Kamaludin Nurul Farahana, and Jotani, Mukesh M. and Tiekink, Edward R. T. * (2018) Crystal structures and Hirshfeld surface analyses of bis[N,N-bis(2-methoxyethyl)dithiocarbamato-κ2 S,S′]di-n-butyltin(IV) and [N-(2-methoxyethyl)-N-methyldithiocarbamato-κ2 S,S′]triphenyltin(IV). Acta Crystallographica Section E Crystallographic Communications, 74 (3). pp. 302-308. ISSN 2056-9890 http://doi.org/10.1107/S2056989018001901 doi:10.1107/S2056989018001901 |
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QD Chemistry Mohamad Rapidah, Awang Normah, Kamaludin Nurul Farahana, Jotani, Mukesh M. Tiekink, Edward R. T. * Crystal structures and Hirshfeld surface analyses of bis[N,N-bis(2-methoxyethyl)dithiocarbamato-κ2 S,S′]di-n-butyltin(IV) and [N-(2-methoxyethyl)-N-methyldithiocarbamato-κ2 S,S′]triphenyltin(IV) |
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The crystal and molecular structures of the two title organotin dithiocarbamate compounds, [Sn(C4H9)2(C7H14NO2S2)2], (I), and [Sn(C6H5)3(C5H10NOS2)], (II), are described. Both structures feature asymmetrically bound dithiocarbamate ligands leading to a skew-trapezoidal bipyramidal geometry for the metal atom in (I) and a distorted tetrahedral geometry in (II). The complete molecule of (I) is generated by a crystallographic twofold axis (Sn site symmetry 2). In the crystal of (I), molecules self-assemble into a supramolecular array parallel to (101) via methylene-C—H...O(methoxy) interactions. In the crystal of (II), supramolecular dimers are formed via pairs of weak phenyl-C—H...π(phenyl) contacts. In each of (I) and (II), the specified assemblies connect into a threedimensional architecture without directional interactions between them. Hirshfeld surface analyses confirm the importance of H...H contacts in the molecular packing of each of (I) and (II), and in the case of (I), highlight the importance of short methoxy-H...H(butyl) contacts between layers. |
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Article |
author |
Mohamad Rapidah, Awang Normah, Kamaludin Nurul Farahana, Jotani, Mukesh M. Tiekink, Edward R. T. * |
author_facet |
Mohamad Rapidah, Awang Normah, Kamaludin Nurul Farahana, Jotani, Mukesh M. Tiekink, Edward R. T. * |
author_sort |
Mohamad Rapidah, |
title |
Crystal structures and Hirshfeld surface analyses of bis[N,N-bis(2-methoxyethyl)dithiocarbamato-κ2 S,S′]di-n-butyltin(IV) and [N-(2-methoxyethyl)-N-methyldithiocarbamato-κ2 S,S′]triphenyltin(IV) |
title_short |
Crystal structures and Hirshfeld surface analyses of bis[N,N-bis(2-methoxyethyl)dithiocarbamato-κ2 S,S′]di-n-butyltin(IV) and [N-(2-methoxyethyl)-N-methyldithiocarbamato-κ2 S,S′]triphenyltin(IV) |
title_full |
Crystal structures and Hirshfeld surface analyses of bis[N,N-bis(2-methoxyethyl)dithiocarbamato-κ2 S,S′]di-n-butyltin(IV) and [N-(2-methoxyethyl)-N-methyldithiocarbamato-κ2 S,S′]triphenyltin(IV) |
title_fullStr |
Crystal structures and Hirshfeld surface analyses of bis[N,N-bis(2-methoxyethyl)dithiocarbamato-κ2 S,S′]di-n-butyltin(IV) and [N-(2-methoxyethyl)-N-methyldithiocarbamato-κ2 S,S′]triphenyltin(IV) |
title_full_unstemmed |
Crystal structures and Hirshfeld surface analyses of bis[N,N-bis(2-methoxyethyl)dithiocarbamato-κ2 S,S′]di-n-butyltin(IV) and [N-(2-methoxyethyl)-N-methyldithiocarbamato-κ2 S,S′]triphenyltin(IV) |
title_sort |
crystal structures and hirshfeld surface analyses of bis[n,n-bis(2-methoxyethyl)dithiocarbamato-κ2 s,s′]di-n-butyltin(iv) and [n-(2-methoxyethyl)-n-methyldithiocarbamato-κ2 s,s′]triphenyltin(iv) |
publishDate |
2018 |
url |
http://eprints.sunway.edu.my/753/1/Tiekink%20Crystal%20structures%20and%20Hirshfeld.pdf http://eprints.sunway.edu.my/753/ http://doi.org/10.1107/S2056989018001901 |
_version_ |
1680323393940881408 |
score |
13.160551 |