Bis(phosphane)copper(I) and silver(I) dithiocarbamates: crystallography and anti-microbial assay

• Main Authors: Nazzatush Shimar Jamaludin,, Siti Nadiah Abdul Halim,, Khoo, Chai-Hoon, Chen, Bao-Jing, See, Tian-Hong, Sim, Jiun-Horng, Cheah, Yoke-Kqueen, Seng, Hoi-Ling *, Tiekink, Edward R. T. *
• Format: Article
• Language: English
• Published: De Gruyter 2016
• Subjects: QD Chemistry
• Online Access: http://eprints.sunway.edu.my/656/1/Z.%20Kristallogr.%202016%20231%20341.pdf; http://eprints.sunway.edu.my/656/; http://dx.doi.org/10.1515/zkri-2016-0003

The crystal and molecular structures of (Ph3P)2M[S2CN(Me)CH2CH2OH], M=Cu, isolated as a 1:1 dichloromethane solvate (1·CH2Cl2), and M=Ag (4) show the central metal atom to be coordinated by a symmetrically (1·CH2Cl2) and asymmetrically chelating (4) dithiocarbamate ligand. The distorted tetrahedral...