Suppression of inhibition of substrate photodegradation by scavengers of hydroxyl radicals: the solvent-cage effect of bromide on nitrate photolysis
In this paper we show that bromide scavenges the (OH)-O-center dot radicals formed upon photolysis of nitrate, before they leave the solvent cage. Bromide can thus inhibit the in-cage recombination between (OH)-O-center dot and (NO2)-N-center dot. The consequence is an increased generation of (NO2)...
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Main Authors: | Radharani, Das, Binay K., Dutta, Valter, Maurino, Davide, Vione, Claudio, Minero |
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Format: | Article |
Published: |
SPRINGER HEIDELBERG, TIERGARTENSTRASSE 17, D-69121 HEIDELBERG, GERMANY
2009
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Online Access: | http://eprints.utp.edu.my/2341/1/SAMPLE_PAPER_PDF.pdf http://apps.isiknowledge.com/full_record.do?product=WOS&search_mode=GeneralSearch&qid=10&SID=X212JDdPAc7358p5C3D&page=1&doc=1 http://eprints.utp.edu.my/2341/ |
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