Photo-triggered sustainable adhesive based on itaconic acid
Photoadhesives have been beneficial for a plethora of applications due to advantages in spatiotemporal control, flexible operating temperature, and in situ applicability. As a sustainable approach, bio-based precursors have been applied for the production of photoadhesives. However, the use of toxic...
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my.utm.1005672023-04-17T07:06:06Z http://eprints.utm.my/id/eprint/100567/ Photo-triggered sustainable adhesive based on itaconic acid Jamaludin, Farah Hidayah Mohd. Yusoff, Noor Izyan Syazana Chida, Hagid Yang, Xuxu Wong, Tuck Whye Zhou, Haofei Li, Tiefeng Wang, Li Goh, Pei Sean Ismail, Ahmad Fauzi TP Chemical technology Photoadhesives have been beneficial for a plethora of applications due to advantages in spatiotemporal control, flexible operating temperature, and in situ applicability. As a sustainable approach, bio-based precursors have been applied for the production of photoadhesives. However, the use of toxic chemicals and incorporation of petroleum-based chemicals in the synthesis process is inevitable. In this study, a photocurable itaconic acid-based polyester, poly(1,3-propanediol-co-citrate-co-itaconate-co-1,12-dodecanedioate) (IAP), was developed from bio-based precursors through a facile, catalyst-free, and solvent-free polycondensation process without use of toxic chemicals. Ultraviolet (UV)-triggered photocross-linking in the presence of a photoinitiator was found to induce adhesion capability in IAP. With 30 min of UV exposure, IAP presented an adhesion strength of 1286.0 ± 19.2 kPa against acrylic substrates. Remarkable adhesion strengths to stainless steel, wood, glass, and polytetrafluoroethylene substrates were also achieved. Due to photo-induced reduction in hydrophilicity of IAP, the polymer was able to repel water at the adhesive-substrate interface upon in situ underwater photocuring, leading to successful wet adhesion. Subsequently, excellent photo-adhesion was also obtained from in situ photocuring of IAP in seawater, simulated body fluid, and silicon oil. This study provides insights into the development of a photo-enhanced and versatile adhesive through green engineering. American Chemical Society 2022 Article PeerReviewed Jamaludin, Farah Hidayah and Mohd. Yusoff, Noor Izyan Syazana and Chida, Hagid and Yang, Xuxu and Wong, Tuck Whye and Zhou, Haofei and Li, Tiefeng and Wang, Li and Goh, Pei Sean and Ismail, Ahmad Fauzi (2022) Photo-triggered sustainable adhesive based on itaconic acid. ACS Sustainable Chemistry and Engineering, 10 (19). pp. 6389-6401. ISSN 2168-0485 http://dx.doi.org/10.1021/acssuschemeng.2c01119 DOI : 10.1021/acssuschemeng.2c01119 |
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TP Chemical technology Jamaludin, Farah Hidayah Mohd. Yusoff, Noor Izyan Syazana Chida, Hagid Yang, Xuxu Wong, Tuck Whye Zhou, Haofei Li, Tiefeng Wang, Li Goh, Pei Sean Ismail, Ahmad Fauzi Photo-triggered sustainable adhesive based on itaconic acid |
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Photoadhesives have been beneficial for a plethora of applications due to advantages in spatiotemporal control, flexible operating temperature, and in situ applicability. As a sustainable approach, bio-based precursors have been applied for the production of photoadhesives. However, the use of toxic chemicals and incorporation of petroleum-based chemicals in the synthesis process is inevitable. In this study, a photocurable itaconic acid-based polyester, poly(1,3-propanediol-co-citrate-co-itaconate-co-1,12-dodecanedioate) (IAP), was developed from bio-based precursors through a facile, catalyst-free, and solvent-free polycondensation process without use of toxic chemicals. Ultraviolet (UV)-triggered photocross-linking in the presence of a photoinitiator was found to induce adhesion capability in IAP. With 30 min of UV exposure, IAP presented an adhesion strength of 1286.0 ± 19.2 kPa against acrylic substrates. Remarkable adhesion strengths to stainless steel, wood, glass, and polytetrafluoroethylene substrates were also achieved. Due to photo-induced reduction in hydrophilicity of IAP, the polymer was able to repel water at the adhesive-substrate interface upon in situ underwater photocuring, leading to successful wet adhesion. Subsequently, excellent photo-adhesion was also obtained from in situ photocuring of IAP in seawater, simulated body fluid, and silicon oil. This study provides insights into the development of a photo-enhanced and versatile adhesive through green engineering. |
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Article |
author |
Jamaludin, Farah Hidayah Mohd. Yusoff, Noor Izyan Syazana Chida, Hagid Yang, Xuxu Wong, Tuck Whye Zhou, Haofei Li, Tiefeng Wang, Li Goh, Pei Sean Ismail, Ahmad Fauzi |
author_facet |
Jamaludin, Farah Hidayah Mohd. Yusoff, Noor Izyan Syazana Chida, Hagid Yang, Xuxu Wong, Tuck Whye Zhou, Haofei Li, Tiefeng Wang, Li Goh, Pei Sean Ismail, Ahmad Fauzi |
author_sort |
Jamaludin, Farah Hidayah |
title |
Photo-triggered sustainable adhesive based on itaconic acid |
title_short |
Photo-triggered sustainable adhesive based on itaconic acid |
title_full |
Photo-triggered sustainable adhesive based on itaconic acid |
title_fullStr |
Photo-triggered sustainable adhesive based on itaconic acid |
title_full_unstemmed |
Photo-triggered sustainable adhesive based on itaconic acid |
title_sort |
photo-triggered sustainable adhesive based on itaconic acid |
publisher |
American Chemical Society |
publishDate |
2022 |
url |
http://eprints.utm.my/id/eprint/100567/ http://dx.doi.org/10.1021/acssuschemeng.2c01119 |
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1765296672138592256 |
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13.15806 |