A study of the kinetics and mechanism of the adsorption and anaerobic partial oxidation of n-butane over a vanadyl pyrophosphate catalyst

• Main Authors: Sakakini, Bahij H., Yap, Taufiq Yun Hin, Waugh, Kenneth Charles
• Format: Article
• Language: English; English
• Published: Elsevier 2000
• Online Access: http://psasir.upm.edu.my/id/eprint/7881/1/A%20study%20of%20the%20kinetics%20and%20mechanism%20of%20the%20adsorption%20and%20anaerobic%20partial%20oxidation%20of%20n-butane%20over%20a%20vanadyl%20pyrophosphate%20catalyst.pdf; http://psasir.upm.edu.my/id/eprint/7881/7/1-s2.0-S0021951799925137-main.pdf; http://psasir.upm.edu.my/id/eprint/7881/; http://dx.doi.org/10.1006/jcat.1999.2513

The interaction of n-butane with a ((VO)2P2O7) catalyst has been investigated by temperature-programmed desorption and anaerobic temperature-programmed reaction. n-Butane has been shown to adsorb on the (VO)2P2O7 to as a butyl–hydroxyl pair. When adsorption is carried out at 223 K, upon temperature...