(N-Benzyl-N-isopropyldithiocarbamato)-chloridodiphenyltin(IV)

The SnIV atom in the title organotin dithio­carbamate, [Sn(C6H5)2(C11H14NS2)Cl], is penta-coordinated by an asymmetrically coordinating dithio­carbamate ligand, a Cl and two ispo-C atoms of the Sn-bound phenyl groups. The resulting C2ClS2 donor set defines a coordination geometry inter­mediate betwe...

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Main Authors: Abdul Muthalib, Amirah Faizah, Baba, Ibrahim, Mohamed Tahir, Mohamed Ibrahim, Seik, Weng Ng, Tiekink, Edward R. T.
Format: Article
Language:English
English
Published: International Union of Crystallography 2010
Online Access:http://psasir.upm.edu.my/id/eprint/12627/1/N-benzy.pdf
http://psasir.upm.edu.my/id/eprint/12627/
http://dx.doi.org/10.1107/S1600536810031636
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spelling my.upm.eprints.126272015-11-03T01:07:04Z http://psasir.upm.edu.my/id/eprint/12627/ (N-Benzyl-N-isopropyldithiocarbamato)-chloridodiphenyltin(IV) Abdul Muthalib, Amirah Faizah Baba, Ibrahim Mohamed Tahir, Mohamed Ibrahim Seik, Weng Ng Tiekink, Edward R. T. The SnIV atom in the title organotin dithio­carbamate, [Sn(C6H5)2(C11H14NS2)Cl], is penta-coordinated by an asymmetrically coordinating dithio­carbamate ligand, a Cl and two ispo-C atoms of the Sn-bound phenyl groups. The resulting C2ClS2 donor set defines a coordination geometry inter­mediate between square-pyramidal and trigonal-bipyramidal with a slight tendency towards the latter. The formation of close intra­molecular C–H[cdots, three dots, centered]Cl and C–H[cdots, three dots, centered]S contacts precludes the Cl and S atoms from forming significant inter­molecular contacts. The presence of C–H[cdots, three dots, centered]π contacts leads to the formation of supra­molecular arrays that stack along the b axis. International Union of Crystallography 2010 Article PeerReviewed application/pdf en http://psasir.upm.edu.my/id/eprint/12627/1/N-benzy.pdf Abdul Muthalib, Amirah Faizah and Baba, Ibrahim and Mohamed Tahir, Mohamed Ibrahim and Seik, Weng Ng and Tiekink, Edward R. T. (2010) (N-Benzyl-N-isopropyldithiocarbamato)-chloridodiphenyltin(IV). Acta Crystallographica Section E: Structure Reports Online, 66 (1087). pp. 1-12. ISSN 1600-5368 http://dx.doi.org/10.1107/S1600536810031636 English
institution Universiti Putra Malaysia
building UPM Library
collection Institutional Repository
continent Asia
country Malaysia
content_provider Universiti Putra Malaysia
content_source UPM Institutional Repository
url_provider http://psasir.upm.edu.my/
language English
English
description The SnIV atom in the title organotin dithio­carbamate, [Sn(C6H5)2(C11H14NS2)Cl], is penta-coordinated by an asymmetrically coordinating dithio­carbamate ligand, a Cl and two ispo-C atoms of the Sn-bound phenyl groups. The resulting C2ClS2 donor set defines a coordination geometry inter­mediate between square-pyramidal and trigonal-bipyramidal with a slight tendency towards the latter. The formation of close intra­molecular C–H[cdots, three dots, centered]Cl and C–H[cdots, three dots, centered]S contacts precludes the Cl and S atoms from forming significant inter­molecular contacts. The presence of C–H[cdots, three dots, centered]π contacts leads to the formation of supra­molecular arrays that stack along the b axis.
format Article
author Abdul Muthalib, Amirah Faizah
Baba, Ibrahim
Mohamed Tahir, Mohamed Ibrahim
Seik, Weng Ng
Tiekink, Edward R. T.
spellingShingle Abdul Muthalib, Amirah Faizah
Baba, Ibrahim
Mohamed Tahir, Mohamed Ibrahim
Seik, Weng Ng
Tiekink, Edward R. T.
(N-Benzyl-N-isopropyldithiocarbamato)-chloridodiphenyltin(IV)
author_facet Abdul Muthalib, Amirah Faizah
Baba, Ibrahim
Mohamed Tahir, Mohamed Ibrahim
Seik, Weng Ng
Tiekink, Edward R. T.
author_sort Abdul Muthalib, Amirah Faizah
title (N-Benzyl-N-isopropyldithiocarbamato)-chloridodiphenyltin(IV)
title_short (N-Benzyl-N-isopropyldithiocarbamato)-chloridodiphenyltin(IV)
title_full (N-Benzyl-N-isopropyldithiocarbamato)-chloridodiphenyltin(IV)
title_fullStr (N-Benzyl-N-isopropyldithiocarbamato)-chloridodiphenyltin(IV)
title_full_unstemmed (N-Benzyl-N-isopropyldithiocarbamato)-chloridodiphenyltin(IV)
title_sort (n-benzyl-n-isopropyldithiocarbamato)-chloridodiphenyltin(iv)
publisher International Union of Crystallography
publishDate 2010
url http://psasir.upm.edu.my/id/eprint/12627/1/N-benzy.pdf
http://psasir.upm.edu.my/id/eprint/12627/
http://dx.doi.org/10.1107/S1600536810031636
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