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(N-Benzyl-N-isopropyldithiocarbamato)-chloridodiphenyltin(IV)

The SnIV atom in the title organotin dithio­carbamate, [Sn(C6H5)2(C11H14NS2)Cl], is penta-coordinated by an asymmetrically coordinating dithio­carbamate ligand, a Cl and two ispo-C atoms of the Sn-bound phenyl groups. The resulting C2ClS2 donor set defines a coordination geometry inter­mediate betwe...

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Bibliographic Details
Main Authors: Abdul Muthalib, Amirah Faizah, Baba, Ibrahim, Mohamed Tahir, Mohamed Ibrahim, Seik, Weng Ng, Tiekink, Edward R. T.
Format: Article
Language:English
English
Published: International Union of Crystallography 2010
Online Access:http://psasir.upm.edu.my/id/eprint/12627/1/N-benzy.pdf
http://psasir.upm.edu.my/id/eprint/12627/
http://dx.doi.org/10.1107/S1600536810031636
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Summary:The SnIV atom in the title organotin dithio­carbamate, [Sn(C6H5)2(C11H14NS2)Cl], is penta-coordinated by an asymmetrically coordinating dithio­carbamate ligand, a Cl and two ispo-C atoms of the Sn-bound phenyl groups. The resulting C2ClS2 donor set defines a coordination geometry inter­mediate between square-pyramidal and trigonal-bipyramidal with a slight tendency towards the latter. The formation of close intra­molecular C–H[cdots, three dots, centered]Cl and C–H[cdots, three dots, centered]S contacts precludes the Cl and S atoms from forming significant inter­molecular contacts. The presence of C–H[cdots, three dots, centered]π contacts leads to the formation of supra­molecular arrays that stack along the b axis.

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