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{2- (2-Carbamothiolylhydrazin-1-ylidene-kappa N-2(1),S)methyl -6-hydroxyphenolato-kappa O-1}(triphenylphosphine-kappa P)nickel(II) chloride

The deprotonated Schiff base ligand in the title compound, [Ni(C8H8N3O2S)(C18H15P)]Cl, functions as an N,O,S-chelating anion to the phosphine-coordinated Ni atom, which exists in a distorted square-planar geometry. The hydroxy group forms an intramolecular O-H center dot center dot center dot O hydr...

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Main Authors: Tan, Kong Wai, Ng, S.W., Shawish, H.B., Maah, Mohd Jamil
Format: Article
Language:English
Published: International Union of Crystallography 2010
Subjects:
QD Chemistry
Online Access:http://eprints.um.edu.my/8027/1/Shawish-2010-%7B2-_%282-Carbamothioly.pdf
http://eprints.um.edu.my/8027/
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spelling my.um.eprints.80272019-01-30T08:54:36Z http://eprints.um.edu.my/8027/ {2- (2-Carbamothiolylhydrazin-1-ylidene-kappa N-2(1),S)methyl -6-hydroxyphenolato-kappa O-1}(triphenylphosphine-kappa P)nickel(II) chloride Tan, Kong Wai Ng, S.W. Shawish, H.B. Maah, Mohd Jamil QD Chemistry The deprotonated Schiff base ligand in the title compound, [Ni(C8H8N3O2S)(C18H15P)]Cl, functions as an N,O,S-chelating anion to the phosphine-coordinated Ni atom, which exists in a distorted square-planar geometry. The hydroxy group forms an intramolecular O-H center dot center dot center dot O hydrogen bond. The two amino groups of the cation are hydrogen-bond donors to the chloride anion; the hydrogen bonds generate a chain structure running along the b axis. International Union of Crystallography 2010 Article PeerReviewed application/pdf en http://eprints.um.edu.my/8027/1/Shawish-2010-%7B2-_%282-Carbamothioly.pdf Tan, Kong Wai and Ng, S.W. and Shawish, H.B. and Maah, Mohd Jamil (2010) {2- (2-Carbamothiolylhydrazin-1-ylidene-kappa N-2(1),S)methyl -6-hydroxyphenolato-kappa O-1}(triphenylphosphine-kappa P)nickel(II) chloride. Acta Crystallographica Section E: Structure Reports Online, 66. M1074-U374. ISSN 1600-5368 10.1107/s1600536810031065
institution Universiti Malaya
building UM Library
collection Institutional Repository
continent Asia
country Malaysia
content_provider Universiti Malaya
content_source UM Research Repository
url_provider http://eprints.um.edu.my/
language English
topic QD Chemistry
spellingShingle QD Chemistry
Tan, Kong Wai
Ng, S.W.
Shawish, H.B.
Maah, Mohd Jamil
{2- (2-Carbamothiolylhydrazin-1-ylidene-kappa N-2(1),S)methyl -6-hydroxyphenolato-kappa O-1}(triphenylphosphine-kappa P)nickel(II) chloride
description The deprotonated Schiff base ligand in the title compound, [Ni(C8H8N3O2S)(C18H15P)]Cl, functions as an N,O,S-chelating anion to the phosphine-coordinated Ni atom, which exists in a distorted square-planar geometry. The hydroxy group forms an intramolecular O-H center dot center dot center dot O hydrogen bond. The two amino groups of the cation are hydrogen-bond donors to the chloride anion; the hydrogen bonds generate a chain structure running along the b axis.
format Article
author Tan, Kong Wai
Ng, S.W.
Shawish, H.B.
Maah, Mohd Jamil
author_facet Tan, Kong Wai
Ng, S.W.
Shawish, H.B.
Maah, Mohd Jamil
author_sort Tan, Kong Wai
title {2- (2-Carbamothiolylhydrazin-1-ylidene-kappa N-2(1),S)methyl -6-hydroxyphenolato-kappa O-1}(triphenylphosphine-kappa P)nickel(II) chloride
title_short {2- (2-Carbamothiolylhydrazin-1-ylidene-kappa N-2(1),S)methyl -6-hydroxyphenolato-kappa O-1}(triphenylphosphine-kappa P)nickel(II) chloride
title_full {2- (2-Carbamothiolylhydrazin-1-ylidene-kappa N-2(1),S)methyl -6-hydroxyphenolato-kappa O-1}(triphenylphosphine-kappa P)nickel(II) chloride
title_fullStr {2- (2-Carbamothiolylhydrazin-1-ylidene-kappa N-2(1),S)methyl -6-hydroxyphenolato-kappa O-1}(triphenylphosphine-kappa P)nickel(II) chloride
title_full_unstemmed {2- (2-Carbamothiolylhydrazin-1-ylidene-kappa N-2(1),S)methyl -6-hydroxyphenolato-kappa O-1}(triphenylphosphine-kappa P)nickel(II) chloride
title_sort {2- (2-carbamothiolylhydrazin-1-ylidene-kappa n-2(1),s)methyl -6-hydroxyphenolato-kappa o-1}(triphenylphosphine-kappa p)nickel(ii) chloride
publisher International Union of Crystallography
publishDate 2010
url http://eprints.um.edu.my/8027/1/Shawish-2010-%7B2-_%282-Carbamothioly.pdf
http://eprints.um.edu.my/8027/
_version_ 1643688197722472448
score 13.211869

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