{2- (2-Carbamothiolylhydrazin-1-ylidene-kappa N-2(1),S)methyl -6-hydroxyphenolato-kappa O-1}(triphenylphosphine-kappa P)nickel(II) chloride

• Main Authors: Tan, Kong Wai, Ng, S.W., Shawish, H.B., Maah, Mohd Jamil
• Format: Article
• Language: English
• Published: International Union of Crystallography 2010
• Subjects: QD Chemistry
• Online Access: http://eprints.um.edu.my/8027/1/Shawish-2010-%7B2-_%282-Carbamothioly.pdf; http://eprints.um.edu.my/8027/

The deprotonated Schiff base ligand in the title compound, [Ni(C8H8N3O2S)(C18H15P)]Cl, functions as an N,O,S-chelating anion to the phosphine-coordinated Ni atom, which exists in a distorted square-planar geometry. The hydroxy group forms an intramolecular O-H center dot center dot center dot O hydr...