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Bis{2 '- (5-chloro-1H-3-indolyl)methylene 2-(1H-3-indolyl)acetohydrazido-kappa N-2,O}nickel(II) dimethyl sulfoxide disolvate

The Ni atom in the title compound, [Ni(C19H14ClN4O)(2)]center dot 2C(2)H(6)OS, which lies on a centre of inversion, is N, O-chelated by the two monoanionic ligands in a square-planar geometry. The asymmetric unit also contains a dimethyl sulfoxide solvent molecule. The donor amino sites of the metal...

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Main Authors: Ali, Hapipah Mohd, Ng, S.W., Rizal, M.R., Nazzatush, J.
Format: Article
Published: International Union of Crystallography 2007
Subjects:
QD Chemistry
Online Access:http://eprints.um.edu.my/5510/
http://scripts.iucr.org/cgi-bin/paper?S1600536807056966
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spelling my.um.eprints.55102019-01-31T01:21:55Z http://eprints.um.edu.my/5510/ Bis{2 '- (5-chloro-1H-3-indolyl)methylene 2-(1H-3-indolyl)acetohydrazido-kappa N-2,O}nickel(II) dimethyl sulfoxide disolvate Ali, Hapipah Mohd Ng, S.W. Rizal, M.R. Nazzatush, J. QD Chemistry The Ni atom in the title compound, [Ni(C19H14ClN4O)(2)]center dot 2C(2)H(6)OS, which lies on a centre of inversion, is N, O-chelated by the two monoanionic ligands in a square-planar geometry. The asymmetric unit also contains a dimethyl sulfoxide solvent molecule. The donor amino sites of the metal-bearing molecule interact with the solvent molecules to furnish a hydrogen-bonded layer structure. International Union of Crystallography 2007 Article PeerReviewed Ali, Hapipah Mohd and Ng, S.W. and Rizal, M.R. and Nazzatush, J. (2007) Bis{2 '- (5-chloro-1H-3-indolyl)methylene 2-(1H-3-indolyl)acetohydrazido-kappa N-2,O}nickel(II) dimethyl sulfoxide disolvate. Acta Crystallographica Section E: Structure Reports Online, 63. M3033-U1568. ISSN 1600-5368 http://scripts.iucr.org/cgi-bin/paper?S1600536807056966 10.1107/s1600536807056966
institution Universiti Malaya
building UM Library
collection Institutional Repository
continent Asia
country Malaysia
content_provider Universiti Malaya
content_source UM Research Repository
url_provider http://eprints.um.edu.my/
topic QD Chemistry
spellingShingle QD Chemistry
Ali, Hapipah Mohd
Ng, S.W.
Rizal, M.R.
Nazzatush, J.
Bis{2 '- (5-chloro-1H-3-indolyl)methylene 2-(1H-3-indolyl)acetohydrazido-kappa N-2,O}nickel(II) dimethyl sulfoxide disolvate
description The Ni atom in the title compound, [Ni(C19H14ClN4O)(2)]center dot 2C(2)H(6)OS, which lies on a centre of inversion, is N, O-chelated by the two monoanionic ligands in a square-planar geometry. The asymmetric unit also contains a dimethyl sulfoxide solvent molecule. The donor amino sites of the metal-bearing molecule interact with the solvent molecules to furnish a hydrogen-bonded layer structure.
format Article
author Ali, Hapipah Mohd
Ng, S.W.
Rizal, M.R.
Nazzatush, J.
author_facet Ali, Hapipah Mohd
Ng, S.W.
Rizal, M.R.
Nazzatush, J.
author_sort Ali, Hapipah Mohd
title Bis{2 '- (5-chloro-1H-3-indolyl)methylene 2-(1H-3-indolyl)acetohydrazido-kappa N-2,O}nickel(II) dimethyl sulfoxide disolvate
title_short Bis{2 '- (5-chloro-1H-3-indolyl)methylene 2-(1H-3-indolyl)acetohydrazido-kappa N-2,O}nickel(II) dimethyl sulfoxide disolvate
title_full Bis{2 '- (5-chloro-1H-3-indolyl)methylene 2-(1H-3-indolyl)acetohydrazido-kappa N-2,O}nickel(II) dimethyl sulfoxide disolvate
title_fullStr Bis{2 '- (5-chloro-1H-3-indolyl)methylene 2-(1H-3-indolyl)acetohydrazido-kappa N-2,O}nickel(II) dimethyl sulfoxide disolvate
title_full_unstemmed Bis{2 '- (5-chloro-1H-3-indolyl)methylene 2-(1H-3-indolyl)acetohydrazido-kappa N-2,O}nickel(II) dimethyl sulfoxide disolvate
title_sort bis{2 '- (5-chloro-1h-3-indolyl)methylene 2-(1h-3-indolyl)acetohydrazido-kappa n-2,o}nickel(ii) dimethyl sulfoxide disolvate
publisher International Union of Crystallography
publishDate 2007
url http://eprints.um.edu.my/5510/
http://scripts.iucr.org/cgi-bin/paper?S1600536807056966
_version_ 1643687596060049408
score 13.160551

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