2-{1- 2-(Bis{2- 1-(5-chloro-2-hydroxyphenyl)ethylideneamino ethyl}amino) ethyliminio ethyl}-4-chlorophenolate toluene hemisolvate
In the toluene hemisolvated tripodal tris(2-aminoethyl) amine Schiff base, C(30)H(33)Cl(3)N(4)O(3 center dot)0.5C(7)H(8), one of the three imino N atoms is protonated, forming a hydrogen bond with the O atom at an adjacent benzene ring. The other two imino N atoms act as hydrogen-bond acceptors from...
Saved in:
Main Authors: | , , , |
---|---|
Format: | Article |
Language: | English |
Published: |
International Union of Crystallography
2009
|
Subjects: | |
Online Access: | http://eprints.um.edu.my/5369/1/Lee-2009-2-%7B1-_2-%28Bis%7B2-_1-%285.pdf http://eprints.um.edu.my/5369/ http://journals.iucr.org/e/issues/2009/02/00/bt2855/bt2855.pdf |
Tags: |
Add Tag
No Tags, Be the first to tag this record!
|
id |
my.um.eprints.5369 |
---|---|
record_format |
eprints |
spelling |
my.um.eprints.53692019-01-29T08:48:11Z http://eprints.um.edu.my/5369/ 2-{1- 2-(Bis{2- 1-(5-chloro-2-hydroxyphenyl)ethylideneamino ethyl}amino) ethyliminio ethyl}-4-chlorophenolate toluene hemisolvate Lee, S.M. Ng, S.W. Lo, K.M. Ali, Hapipah Mohd QD Chemistry In the toluene hemisolvated tripodal tris(2-aminoethyl) amine Schiff base, C(30)H(33)Cl(3)N(4)O(3 center dot)0.5C(7)H(8), one of the three imino N atoms is protonated, forming a hydrogen bond with the O atom at an adjacent benzene ring. The other two imino N atoms act as hydrogen-bond acceptors from phenolate OH groups. The toluene solvent molecule is disordered about a centre of inversion. International Union of Crystallography 2009 Article PeerReviewed application/pdf en http://eprints.um.edu.my/5369/1/Lee-2009-2-%7B1-_2-%28Bis%7B2-_1-%285.pdf Lee, S.M. and Ng, S.W. and Lo, K.M. and Ali, Hapipah Mohd (2009) 2-{1- 2-(Bis{2- 1-(5-chloro-2-hydroxyphenyl)ethylideneamino ethyl}amino) ethyliminio ethyl}-4-chlorophenolate toluene hemisolvate. Acta Crystallographica Section E: Structure Reports Online, 65. O409-U2928. ISSN 1600-5368 http://journals.iucr.org/e/issues/2009/02/00/bt2855/bt2855.pdf 10.1107/s1600536809002906 |
institution |
Universiti Malaya |
building |
UM Library |
collection |
Institutional Repository |
continent |
Asia |
country |
Malaysia |
content_provider |
Universiti Malaya |
content_source |
UM Research Repository |
url_provider |
http://eprints.um.edu.my/ |
language |
English |
topic |
QD Chemistry |
spellingShingle |
QD Chemistry Lee, S.M. Ng, S.W. Lo, K.M. Ali, Hapipah Mohd 2-{1- 2-(Bis{2- 1-(5-chloro-2-hydroxyphenyl)ethylideneamino ethyl}amino) ethyliminio ethyl}-4-chlorophenolate toluene hemisolvate |
description |
In the toluene hemisolvated tripodal tris(2-aminoethyl) amine Schiff base, C(30)H(33)Cl(3)N(4)O(3 center dot)0.5C(7)H(8), one of the three imino N atoms is protonated, forming a hydrogen bond with the O atom at an adjacent benzene ring. The other two imino N atoms act as hydrogen-bond acceptors from phenolate OH groups. The toluene solvent molecule is disordered about a centre of inversion. |
format |
Article |
author |
Lee, S.M. Ng, S.W. Lo, K.M. Ali, Hapipah Mohd |
author_facet |
Lee, S.M. Ng, S.W. Lo, K.M. Ali, Hapipah Mohd |
author_sort |
Lee, S.M. |
title |
2-{1- 2-(Bis{2- 1-(5-chloro-2-hydroxyphenyl)ethylideneamino ethyl}amino) ethyliminio ethyl}-4-chlorophenolate toluene hemisolvate |
title_short |
2-{1- 2-(Bis{2- 1-(5-chloro-2-hydroxyphenyl)ethylideneamino ethyl}amino) ethyliminio ethyl}-4-chlorophenolate toluene hemisolvate |
title_full |
2-{1- 2-(Bis{2- 1-(5-chloro-2-hydroxyphenyl)ethylideneamino ethyl}amino) ethyliminio ethyl}-4-chlorophenolate toluene hemisolvate |
title_fullStr |
2-{1- 2-(Bis{2- 1-(5-chloro-2-hydroxyphenyl)ethylideneamino ethyl}amino) ethyliminio ethyl}-4-chlorophenolate toluene hemisolvate |
title_full_unstemmed |
2-{1- 2-(Bis{2- 1-(5-chloro-2-hydroxyphenyl)ethylideneamino ethyl}amino) ethyliminio ethyl}-4-chlorophenolate toluene hemisolvate |
title_sort |
2-{1- 2-(bis{2- 1-(5-chloro-2-hydroxyphenyl)ethylideneamino ethyl}amino) ethyliminio ethyl}-4-chlorophenolate toluene hemisolvate |
publisher |
International Union of Crystallography |
publishDate |
2009 |
url |
http://eprints.um.edu.my/5369/1/Lee-2009-2-%7B1-_2-%28Bis%7B2-_1-%285.pdf http://eprints.um.edu.my/5369/ http://journals.iucr.org/e/issues/2009/02/00/bt2855/bt2855.pdf |
_version_ |
1643687558311313408 |
score |
13.211869 |