2-{1- 2-(Bis{2- 1-(5-chloro-2-hydroxyphenyl)ethylideneamino ethyl}amino) ethyliminio ethyl}-4-chlorophenolate toluene hemisolvate

In the toluene hemisolvated tripodal tris(2-aminoethyl) amine Schiff base, C(30)H(33)Cl(3)N(4)O(3 center dot)0.5C(7)H(8), one of the three imino N atoms is protonated, forming a hydrogen bond with the O atom at an adjacent benzene ring. The other two imino N atoms act as hydrogen-bond acceptors from...

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Bibliographic Details
Main Authors: Lee, S.M., Ng, S.W., Lo, K.M., Ali, Hapipah Mohd
Format: Article
Language:English
Published: International Union of Crystallography 2009
Subjects:
Online Access:http://eprints.um.edu.my/5369/1/Lee-2009-2-%7B1-_2-%28Bis%7B2-_1-%285.pdf
http://eprints.um.edu.my/5369/
http://journals.iucr.org/e/issues/2009/02/00/bt2855/bt2855.pdf
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Summary:In the toluene hemisolvated tripodal tris(2-aminoethyl) amine Schiff base, C(30)H(33)Cl(3)N(4)O(3 center dot)0.5C(7)H(8), one of the three imino N atoms is protonated, forming a hydrogen bond with the O atom at an adjacent benzene ring. The other two imino N atoms act as hydrogen-bond acceptors from phenolate OH groups. The toluene solvent molecule is disordered about a centre of inversion.