Bis{benzyl 3- (1H-indol-3-yl)methylidene dithiocarbazato-kappa N-2(3),S}palladium(II) pyridine disolvate

• Main Authors: Khaledi, H., Ali, Hapipah Mohd
• Format: Article
• Language: English
• Published: International Union of Crystallography 2011
• Subjects: QD Chemistry
• Online Access: http://eprints.um.edu.my/5223/1/Khaledi-2011-Bis%7Bbenzyl_3-_%281H-in.pdf; http://eprints.um.edu.my/5223/; http://journals.iucr.org/e/issues/2011/02/00/issconts.html; http://dx.doi.org/10.1107/s1600536811001991

The Pd-II ion in the title compound, [Pd(C17H14N3S2)(2)]center dot 2C(5)H(5)N, is located on an inversion center and is four-coordinated by two of the deprotonated N,S-bidentate Schiff base ligands in a square-planar geometry. The dihedral angle between the aromatic ring planes within the ligand is 71.12 (9)degrees. The indole NH groups are bonded to the pyridine solvent molecules via an N-H center dot center dot center dot N interaction. The crystal structure is consolidated by intermolecular C-H center dot center dot center dot S interactions.