Bis{benzyl 3- (1H-indol-3-yl)methylidene dithiocarbazato-kappa N-2(3),S}palladium(II) pyridine disolvate
The Pd-II ion in the title compound, [Pd(C17H14N3S2)(2)]center dot 2C(5)H(5)N, is located on an inversion center and is four-coordinated by two of the deprotonated N,S-bidentate Schiff base ligands in a square-planar geometry. The dihedral angle between the aromatic ring planes within the ligand is...
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| Main Authors: | , |
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| Format: | Article |
| Language: | English |
| Published: |
International Union of Crystallography
2011
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| Subjects: | |
| Online Access: | http://eprints.um.edu.my/5223/1/Khaledi-2011-Bis%7Bbenzyl_3-_%281H-in.pdf http://eprints.um.edu.my/5223/ http://journals.iucr.org/e/issues/2011/02/00/issconts.html http://dx.doi.org/10.1107/s1600536811001991 |
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| Summary: | The Pd-II ion in the title compound, [Pd(C17H14N3S2)(2)]center dot 2C(5)H(5)N, is located on an inversion center and is four-coordinated by two of the deprotonated N,S-bidentate Schiff base ligands in a square-planar geometry. The dihedral angle between the aromatic ring planes within the ligand is 71.12 (9)degrees. The indole NH groups are bonded to the pyridine solvent molecules via an N-H center dot center dot center dot N interaction. The crystal structure is consolidated by intermolecular C-H center dot center dot center dot S interactions. |
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