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Tris[2,5-bis(1H-benzimidazol-2-yl)pyridinato-κ2 N 1,N 2]cobalt(III) dihydrate

In the title compound, [Co(C19H12N5) 3]·2H2O, three mono-deprotonated 2,5-bis(benzimidazolyl)pyridine heterocycles chelate to cobalt(III) through the N atom of one benzimidazolyl arm of the heterocycle as well as through the pyridyl N atom to form a fairly regular six-coordinate, octahedral geometry...

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Main Authors: Zhou, Yan-Ling, Zeng, Ming-Hua, Ng, Seik Weng
Format: Article
Published: International Union of Crystallography 2006
Subjects:
Q Science (General)
QD Chemistry
Online Access:http://eprints.um.edu.my/25281/
https://doi.org/10.1107/S1600536806007082
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spelling my.um.eprints.252812020-08-06T06:33:27Z http://eprints.um.edu.my/25281/ Tris[2,5-bis(1H-benzimidazol-2-yl)pyridinato-κ2 N 1,N 2]cobalt(III) dihydrate Zhou, Yan-Ling Zeng, Ming-Hua Ng, Seik Weng Q Science (General) QD Chemistry In the title compound, [Co(C19H12N5) 3]·2H2O, three mono-deprotonated 2,5-bis(benzimidazolyl)pyridine heterocycles chelate to cobalt(III) through the N atom of one benzimidazolyl arm of the heterocycle as well as through the pyridyl N atom to form a fairly regular six-coordinate, octahedral geometry geometry for cobalt. A network of N-H⋯N, N H⋯O and O -H⋯N hydrogen bonds involving the non-coordinated water molecules results in a layered structure. © 2006 International Union of Crystallography All rights reserved. International Union of Crystallography 2006 Article PeerReviewed Zhou, Yan-Ling and Zeng, Ming-Hua and Ng, Seik Weng (2006) Tris[2,5-bis(1H-benzimidazol-2-yl)pyridinato-κ2 N 1,N 2]cobalt(III) dihydrate. Acta Crystallographica Section E: Structure Reports Online, 62 (4). m663-m665. ISSN 1600-5368 https://doi.org/10.1107/S1600536806007082 doi:10.1107/S1600536806007082
institution Universiti Malaya
building UM Library
collection Institutional Repository
continent Asia
country Malaysia
content_provider Universiti Malaya
content_source UM Research Repository
url_provider http://eprints.um.edu.my/
topic Q Science (General)
QD Chemistry
spellingShingle Q Science (General)
QD Chemistry
Zhou, Yan-Ling
Zeng, Ming-Hua
Ng, Seik Weng
Tris[2,5-bis(1H-benzimidazol-2-yl)pyridinato-κ2 N 1,N 2]cobalt(III) dihydrate
description In the title compound, [Co(C19H12N5) 3]·2H2O, three mono-deprotonated 2,5-bis(benzimidazolyl)pyridine heterocycles chelate to cobalt(III) through the N atom of one benzimidazolyl arm of the heterocycle as well as through the pyridyl N atom to form a fairly regular six-coordinate, octahedral geometry geometry for cobalt. A network of N-H⋯N, N H⋯O and O -H⋯N hydrogen bonds involving the non-coordinated water molecules results in a layered structure. © 2006 International Union of Crystallography All rights reserved.
format Article
author Zhou, Yan-Ling
Zeng, Ming-Hua
Ng, Seik Weng
author_facet Zhou, Yan-Ling
Zeng, Ming-Hua
Ng, Seik Weng
author_sort Zhou, Yan-Ling
title Tris[2,5-bis(1H-benzimidazol-2-yl)pyridinato-κ2 N 1,N 2]cobalt(III) dihydrate
title_short Tris[2,5-bis(1H-benzimidazol-2-yl)pyridinato-κ2 N 1,N 2]cobalt(III) dihydrate
title_full Tris[2,5-bis(1H-benzimidazol-2-yl)pyridinato-κ2 N 1,N 2]cobalt(III) dihydrate
title_fullStr Tris[2,5-bis(1H-benzimidazol-2-yl)pyridinato-κ2 N 1,N 2]cobalt(III) dihydrate
title_full_unstemmed Tris[2,5-bis(1H-benzimidazol-2-yl)pyridinato-κ2 N 1,N 2]cobalt(III) dihydrate
title_sort tris[2,5-bis(1h-benzimidazol-2-yl)pyridinato-κ2 n 1,n 2]cobalt(iii) dihydrate
publisher International Union of Crystallography
publishDate 2006
url http://eprints.um.edu.my/25281/
https://doi.org/10.1107/S1600536806007082
_version_ 1680857015645110272
score 13.211869

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