Tris[2,5-bis(1H-benzimidazol-2-yl)pyridinato-κ2 N 1,N 2]cobalt(III) dihydrate
In the title compound, [Co(C19H12N5) 3]·2H2O, three mono-deprotonated 2,5-bis(benzimidazolyl)pyridine heterocycles chelate to cobalt(III) through the N atom of one benzimidazolyl arm of the heterocycle as well as through the pyridyl N atom to form a fairly regular six-coordinate, octahedral geometry...
Saved in:
| Main Authors: | , , |
|---|---|
| Format: | Article |
| Published: |
International Union of Crystallography
2006
|
| Subjects: | |
| Online Access: | http://eprints.um.edu.my/25281/ https://doi.org/10.1107/S1600536806007082 |
| Tags: |
Add Tag
No Tags, Be the first to tag this record!
|
| Summary: | In the title compound, [Co(C19H12N5) 3]·2H2O, three mono-deprotonated 2,5-bis(benzimidazolyl)pyridine heterocycles chelate to cobalt(III) through the N atom of one benzimidazolyl arm of the heterocycle as well as through the pyridyl N atom to form a fairly regular six-coordinate, octahedral geometry geometry for cobalt. A network of N-H⋯N, N H⋯O and O -H⋯N hydrogen bonds involving the non-coordinated water molecules results in a layered structure. © 2006 International Union of Crystallography All rights reserved. |
|---|