Nitrophenylcarbenes. Part I. The catalytic and photolytic decomposition of α-diazo-3-nitrotoluene in the presence of olefins

The decomposition of α-diazo-3-nitrotoluene by zinc halides in the presence of olefins gave cyclopropane adducts in moderate yields. The addition of the carbenoid intermediate to unsymmetrically substituted olefins is syn-stereoselective. The free carbene species generated by photolysis also added r...

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Bibliographic Details
Main Author: Goh, S.H.
Format: Article
Published: Royal Society of Chemistry 1971
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Online Access:http://eprints.um.edu.my/24417/
https://doi.org/10.1039/J39710002275
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