The induced decomposition of t-butyl peroxide in solution. Part III. Decomposition of t-butyl peroxide in alkyl benzyl ethers; steric effects
Product and rate studies of the thermal decomposition of t-butyl peroxide in a series of alkyl benzyl ethers PhCH2·OR (R = Me, Et, Pri, But, or Ph) show little induced decomposition of the peroxide by the ether radical PhĊHOR, whereas in the case of the chloro-substituted ethers ArCH2·OR (Ar = 4-ClC...
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Main Authors: | , , , |
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Format: | Article |
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Royal Society of Chemistry
1971
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Online Access: | http://eprints.um.edu.my/24416/ https://doi.org/10.1039/J39710002282 |
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