Excimer and exciplex formation in a pair of bright phosphorescent isomers constructed from Cu3(pyrazolate)3 and Cu3I3 coordination luminophores

Reported herein are a pair of supramolecular pseudo-isomers, namely, (Cu 3I 3)(Cu 3L 3) 2· H 2O (1) and (Cu 3I 3)(Cu 3L 3) 2 (2) (L = 3-(4-pyridyl)-5-isobutyl-pyrazolate), both of which incorporate Cu 3Pz 3 (Pz = pyrazolate) and Cu 3I 3 clusters as luminophores. The two complexes show distinct yello...

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Main Authors: Zhan, Shun-Ze, Li, Mian, Zhou, Xiao-Ping, Li, Dan, Ng, Seik Weng
Format: Article
Published: Royal Society of Chemistry 2011
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Online Access:http://eprints.um.edu.my/23008/
https://doi.org/10.1039/c1ra00566a
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