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Catena-Poly[[bis-(dimethyl sulfoxide-κO)cerium(III)]tris- (μ2-3,5-dinitro-benzoato-κ2 O:O′)]

The polymeric title compound, [Ce(C7H3N 2O6)3(C2H6OS) 2] n, exists as a linear chain along [111] as the three dinitro-benzoate anions each engages in bridging adjacent dimethyl sulfoxide (DMSO) coordinated CeIII atoms. The metal atoms are surrounded by eight O atoms in a square-anti-prismatic enviro...

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Main Authors: Zhou, Fu Lin, Du, Zhi Hua, Ng, Seik Weng
Format: Article
Published: International Union of Crystallography 2011
Subjects:
Q Science (General)
QD Chemistry
Online Access:http://eprints.um.edu.my/1922/
https://doi.org/10.1107/S1600536811015947
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spelling my.um.eprints.19222019-11-14T03:04:04Z http://eprints.um.edu.my/1922/ Catena-Poly[[bis-(dimethyl sulfoxide-κO)cerium(III)]tris- (μ2-3,5-dinitro-benzoato-κ2 O:O′)] Zhou, Fu Lin Du, Zhi Hua Ng, Seik Weng Q Science (General) QD Chemistry The polymeric title compound, [Ce(C7H3N 2O6)3(C2H6OS) 2] n, exists as a linear chain along [111] as the three dinitro-benzoate anions each engages in bridging adjacent dimethyl sulfoxide (DMSO) coordinated CeIII atoms. The metal atoms are surrounded by eight O atoms in a square-anti-prismatic environment. There are two independent formula units in the asymmetric unit. The S atoms of two of the four DMSO mol-ecules are disordered in a 0.926 (3):0.074 (3) ratio. International Union of Crystallography 2011 Article PeerReviewed Zhou, Fu Lin and Du, Zhi Hua and Ng, Seik Weng (2011) Catena-Poly[[bis-(dimethyl sulfoxide-κO)cerium(III)]tris- (μ2-3,5-dinitro-benzoato-κ2 O:O′)]. Acta Crystallographica Section E: Structure Reports Online, 67 (6). m673. ISSN 1600-5368 https://doi.org/10.1107/S1600536811015947 doi:10.1107/S1600536811015947
institution Universiti Malaya
building UM Library
collection Institutional Repository
continent Asia
country Malaysia
content_provider Universiti Malaya
content_source UM Research Repository
url_provider http://eprints.um.edu.my/
topic Q Science (General)
QD Chemistry
spellingShingle Q Science (General)
QD Chemistry
Zhou, Fu Lin
Du, Zhi Hua
Ng, Seik Weng
Catena-Poly[[bis-(dimethyl sulfoxide-κO)cerium(III)]tris- (μ2-3,5-dinitro-benzoato-κ2 O:O′)]
description The polymeric title compound, [Ce(C7H3N 2O6)3(C2H6OS) 2] n, exists as a linear chain along [111] as the three dinitro-benzoate anions each engages in bridging adjacent dimethyl sulfoxide (DMSO) coordinated CeIII atoms. The metal atoms are surrounded by eight O atoms in a square-anti-prismatic environment. There are two independent formula units in the asymmetric unit. The S atoms of two of the four DMSO mol-ecules are disordered in a 0.926 (3):0.074 (3) ratio.
format Article
author Zhou, Fu Lin
Du, Zhi Hua
Ng, Seik Weng
author_facet Zhou, Fu Lin
Du, Zhi Hua
Ng, Seik Weng
author_sort Zhou, Fu Lin
title Catena-Poly[[bis-(dimethyl sulfoxide-κO)cerium(III)]tris- (μ2-3,5-dinitro-benzoato-κ2 O:O′)]
title_short Catena-Poly[[bis-(dimethyl sulfoxide-κO)cerium(III)]tris- (μ2-3,5-dinitro-benzoato-κ2 O:O′)]
title_full Catena-Poly[[bis-(dimethyl sulfoxide-κO)cerium(III)]tris- (μ2-3,5-dinitro-benzoato-κ2 O:O′)]
title_fullStr Catena-Poly[[bis-(dimethyl sulfoxide-κO)cerium(III)]tris- (μ2-3,5-dinitro-benzoato-κ2 O:O′)]
title_full_unstemmed Catena-Poly[[bis-(dimethyl sulfoxide-κO)cerium(III)]tris- (μ2-3,5-dinitro-benzoato-κ2 O:O′)]
title_sort catena-poly[[bis-(dimethyl sulfoxide-κo)cerium(iii)]tris- (μ2-3,5-dinitro-benzoato-κ2 o:o′)]
publisher International Union of Crystallography
publishDate 2011
url http://eprints.um.edu.my/1922/
https://doi.org/10.1107/S1600536811015947
_version_ 1651867302147129344
score 13.211869

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