Catena-Poly[[bis-(dimethyl sulfoxide-κO)cerium(III)]tris- (μ2-3,5-dinitro-benzoato-κ2 O:O′)]
The polymeric title compound, [Ce(C7H3N 2O6)3(C2H6OS) 2] n, exists as a linear chain along [111] as the three dinitro-benzoate anions each engages in bridging adjacent dimethyl sulfoxide (DMSO) coordinated CeIII atoms. The metal atoms are surrounded by eight O atoms in a square-anti-prismatic enviro...
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| Main Authors: | , , |
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| Format: | Article |
| Published: |
International Union of Crystallography
2011
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| Subjects: | |
| Online Access: | http://eprints.um.edu.my/1922/ https://doi.org/10.1107/S1600536811015947 |
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| Summary: | The polymeric title compound, [Ce(C7H3N 2O6)3(C2H6OS) 2] n, exists as a linear chain along [111] as the three dinitro-benzoate anions each engages in bridging adjacent dimethyl sulfoxide (DMSO) coordinated CeIII atoms. The metal atoms are surrounded by eight O atoms in a square-anti-prismatic environment. There are two independent formula units in the asymmetric unit. The S atoms of two of the four DMSO mol-ecules are disordered in a 0.926 (3):0.074 (3) ratio. |
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