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Synthesis, crystal structure and characterization of a lanthanide complex based on 4-(4-oxypyridinium-1-yl) phthalic acid and 1,10-phenanthroline

A new lanthanide complex [(Ho(L)(phen)NO3(H2O)] H2O (1) (H2L D 4-(4-Oxypyridinium -1-yl) phthalic acid, phen D 1,10-phenanthroline) has been afforded under hydrothermal conditions, and characterized by elemental analysis, IR spectra, and X-ray diffraction. In the structure of 1, the L ligand connect...

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Main Authors: Zhang, T., Li, R.F., Feng, X., Ng, S.W., Bai, RF.
Format: Article
Published: Taylor & Francis 2017
Subjects:
Q Science (General)
QD Chemistry
Online Access:http://eprints.um.edu.my/18814/
http://dx.doi.org/10.1080/15533174.2016.1186065
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spelling my.um.eprints.188142018-06-06T06:41:52Z http://eprints.um.edu.my/18814/ Synthesis, crystal structure and characterization of a lanthanide complex based on 4-(4-oxypyridinium-1-yl) phthalic acid and 1,10-phenanthroline Zhang, T. Li, R.F. Feng, X. Ng, S.W. Bai, RF. Q Science (General) QD Chemistry A new lanthanide complex [(Ho(L)(phen)NO3(H2O)] H2O (1) (H2L D 4-(4-Oxypyridinium -1-yl) phthalic acid, phen D 1,10-phenanthroline) has been afforded under hydrothermal conditions, and characterized by elemental analysis, IR spectra, and X-ray diffraction. In the structure of 1, the L ligand connects Ho(III) atoms through one monodentate and one chelate carboxylate as well as one hydroxy group giving rise to a 2D wavelike polymer layer, which is extended by C–H O hydrogen bond and π π stacking interactions to give rise to a 3D supramolecular network. In addition, PXRD patterns and thermal gravimetric analysis (TGA) of sample 1 were investigated. Taylor & Francis 2017 Article PeerReviewed Zhang, T. and Li, R.F. and Feng, X. and Ng, S.W. and Bai, RF. (2017) Synthesis, crystal structure and characterization of a lanthanide complex based on 4-(4-oxypyridinium-1-yl) phthalic acid and 1,10-phenanthroline. Inorganic and Nano-Metal Chemistry, 47 (3). pp. 375-379. ISSN 2470-1556 http://dx.doi.org/10.1080/15533174.2016.1186065 doi:10.1080/15533174.2016.1186065
institution Universiti Malaya
building UM Library
collection Institutional Repository
continent Asia
country Malaysia
content_provider Universiti Malaya
content_source UM Research Repository
url_provider http://eprints.um.edu.my/
topic Q Science (General)
QD Chemistry
spellingShingle Q Science (General)
QD Chemistry
Zhang, T.
Li, R.F.
Feng, X.
Ng, S.W.
Bai, RF.
Synthesis, crystal structure and characterization of a lanthanide complex based on 4-(4-oxypyridinium-1-yl) phthalic acid and 1,10-phenanthroline
description A new lanthanide complex [(Ho(L)(phen)NO3(H2O)] H2O (1) (H2L D 4-(4-Oxypyridinium -1-yl) phthalic acid, phen D 1,10-phenanthroline) has been afforded under hydrothermal conditions, and characterized by elemental analysis, IR spectra, and X-ray diffraction. In the structure of 1, the L ligand connects Ho(III) atoms through one monodentate and one chelate carboxylate as well as one hydroxy group giving rise to a 2D wavelike polymer layer, which is extended by C–H O hydrogen bond and π π stacking interactions to give rise to a 3D supramolecular network. In addition, PXRD patterns and thermal gravimetric analysis (TGA) of sample 1 were investigated.
format Article
author Zhang, T.
Li, R.F.
Feng, X.
Ng, S.W.
Bai, RF.
author_facet Zhang, T.
Li, R.F.
Feng, X.
Ng, S.W.
Bai, RF.
author_sort Zhang, T.
title Synthesis, crystal structure and characterization of a lanthanide complex based on 4-(4-oxypyridinium-1-yl) phthalic acid and 1,10-phenanthroline
title_short Synthesis, crystal structure and characterization of a lanthanide complex based on 4-(4-oxypyridinium-1-yl) phthalic acid and 1,10-phenanthroline
title_full Synthesis, crystal structure and characterization of a lanthanide complex based on 4-(4-oxypyridinium-1-yl) phthalic acid and 1,10-phenanthroline
title_fullStr Synthesis, crystal structure and characterization of a lanthanide complex based on 4-(4-oxypyridinium-1-yl) phthalic acid and 1,10-phenanthroline
title_full_unstemmed Synthesis, crystal structure and characterization of a lanthanide complex based on 4-(4-oxypyridinium-1-yl) phthalic acid and 1,10-phenanthroline
title_sort synthesis, crystal structure and characterization of a lanthanide complex based on 4-(4-oxypyridinium-1-yl) phthalic acid and 1,10-phenanthroline
publisher Taylor & Francis
publishDate 2017
url http://eprints.um.edu.my/18814/
http://dx.doi.org/10.1080/15533174.2016.1186065
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score 13.160551

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