Synthesis, crystal structure and characterization of a lanthanide complex based on 4-(4-oxypyridinium-1-yl) phthalic acid and 1,10-phenanthroline
A new lanthanide complex [(Ho(L)(phen)NO3(H2O)] H2O (1) (H2L D 4-(4-Oxypyridinium -1-yl) phthalic acid, phen D 1,10-phenanthroline) has been afforded under hydrothermal conditions, and characterized by elemental analysis, IR spectra, and X-ray diffraction. In the structure of 1, the L ligand connect...
Saved in:
Main Authors: | , , , , |
---|---|
Format: | Article |
Published: |
Taylor & Francis
2017
|
Subjects: | |
Online Access: | http://eprints.um.edu.my/18814/ http://dx.doi.org/10.1080/15533174.2016.1186065 |
Tags: |
Add Tag
No Tags, Be the first to tag this record!
|
Summary: | A new lanthanide complex [(Ho(L)(phen)NO3(H2O)] H2O (1) (H2L D 4-(4-Oxypyridinium -1-yl) phthalic acid, phen D 1,10-phenanthroline) has been afforded under hydrothermal conditions, and characterized by elemental analysis, IR spectra, and X-ray diffraction. In the structure of 1, the L ligand connects Ho(III) atoms through one monodentate and one chelate carboxylate as well as one hydroxy group giving rise to a 2D wavelike polymer layer, which is extended by C–H O hydrogen bond and π π stacking interactions to give rise to a 3D supramolecular network. In addition, PXRD patterns and thermal gravimetric analysis (TGA) of sample 1 were investigated. |
---|