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A 3D mixed-valence Cu(I)/Cu(II) coordination polymer constructed by 2-(2-fluorophenyl)-1H-imidazo[4,5-f][1,10]phenanthroline and 1,3-benzenedicarboxylate

A mixed-valence Cu(I)/Cu(II) coordination polymer, namely, [Cu-2(L)(1,3-BDC)](n) (1), has been synthesized under hydrothermal conditions (HL = 2-(2-fluorophenyl)-1H-imidazo[4,5-f][1,10]phenanthroline and 1,3-H2BDC = 1,3-benzenedicarboxylic acid). Its structure has been determined by single crystal X...

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Main Authors: Kong, Z.G., Guo, S.N., Sun, B., Ng, S.W.
Format: Article
Published: 2015
Subjects:
QD Chemistry
Online Access:http://eprints.um.edu.my/16457/
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spelling my.um.eprints.164572016-09-15T04:15:34Z http://eprints.um.edu.my/16457/ A 3D mixed-valence Cu(I)/Cu(II) coordination polymer constructed by 2-(2-fluorophenyl)-1H-imidazo[4,5-f][1,10]phenanthroline and 1,3-benzenedicarboxylate Kong, Z.G. Guo, S.N. Sun, B. Ng, S.W. QD Chemistry A mixed-valence Cu(I)/Cu(II) coordination polymer, namely, [Cu-2(L)(1,3-BDC)](n) (1), has been synthesized under hydrothermal conditions (HL = 2-(2-fluorophenyl)-1H-imidazo[4,5-f][1,10]phenanthroline and 1,3-H2BDC = 1,3-benzenedicarboxylic acid). Its structure has been determined by single crystal X-ray diffraction analysis and powder X-ray diffraction. The crystals are the monoclinic space group P2(1)/c with a = 10.686(4), b = 17.376(8), c = 11.759(4) angstrom, beta = 92.072(14)degrees, C27H14Cu2FN4O4, M-r = 604.50, V = 2182.1(15) angstrom(3), Z = 4, D-calcd. = 1.84 g cm(-3), R = 0.0588 and wR = 0.1202 (all data). In complex 1, the mixed-valence Cu(I)/Cu(II) atoms are linked by L and 1,3-BDC to give a rare 3D (3,3,4)-connected (4.7.9)(7.8.9)(4.7.8.9(3)) framework. The temperature-dependent magnetic susceptibility of 1 was investigated in the temperature range of 2-300 K. 2015 Article PeerReviewed Kong, Z.G. and Guo, S.N. and Sun, B. and Ng, S.W. (2015) A 3D mixed-valence Cu(I)/Cu(II) coordination polymer constructed by 2-(2-fluorophenyl)-1H-imidazo[4,5-f][1,10]phenanthroline and 1,3-benzenedicarboxylate. Zeitschrift Fur Naturforschung Section B-A Journal of Chemical Sciences, 70 (12). pp. 857-861. ISSN 0932-0776 DOI: 10.1515/znb-2015-0095
institution Universiti Malaya
building UM Library
collection Institutional Repository
continent Asia
country Malaysia
content_provider Universiti Malaya
content_source UM Research Repository
url_provider http://eprints.um.edu.my/
topic QD Chemistry
spellingShingle QD Chemistry
Kong, Z.G.
Guo, S.N.
Sun, B.
Ng, S.W.
A 3D mixed-valence Cu(I)/Cu(II) coordination polymer constructed by 2-(2-fluorophenyl)-1H-imidazo[4,5-f][1,10]phenanthroline and 1,3-benzenedicarboxylate
description A mixed-valence Cu(I)/Cu(II) coordination polymer, namely, [Cu-2(L)(1,3-BDC)](n) (1), has been synthesized under hydrothermal conditions (HL = 2-(2-fluorophenyl)-1H-imidazo[4,5-f][1,10]phenanthroline and 1,3-H2BDC = 1,3-benzenedicarboxylic acid). Its structure has been determined by single crystal X-ray diffraction analysis and powder X-ray diffraction. The crystals are the monoclinic space group P2(1)/c with a = 10.686(4), b = 17.376(8), c = 11.759(4) angstrom, beta = 92.072(14)degrees, C27H14Cu2FN4O4, M-r = 604.50, V = 2182.1(15) angstrom(3), Z = 4, D-calcd. = 1.84 g cm(-3), R = 0.0588 and wR = 0.1202 (all data). In complex 1, the mixed-valence Cu(I)/Cu(II) atoms are linked by L and 1,3-BDC to give a rare 3D (3,3,4)-connected (4.7.9)(7.8.9)(4.7.8.9(3)) framework. The temperature-dependent magnetic susceptibility of 1 was investigated in the temperature range of 2-300 K.
format Article
author Kong, Z.G.
Guo, S.N.
Sun, B.
Ng, S.W.
author_facet Kong, Z.G.
Guo, S.N.
Sun, B.
Ng, S.W.
author_sort Kong, Z.G.
title A 3D mixed-valence Cu(I)/Cu(II) coordination polymer constructed by 2-(2-fluorophenyl)-1H-imidazo[4,5-f][1,10]phenanthroline and 1,3-benzenedicarboxylate
title_short A 3D mixed-valence Cu(I)/Cu(II) coordination polymer constructed by 2-(2-fluorophenyl)-1H-imidazo[4,5-f][1,10]phenanthroline and 1,3-benzenedicarboxylate
title_full A 3D mixed-valence Cu(I)/Cu(II) coordination polymer constructed by 2-(2-fluorophenyl)-1H-imidazo[4,5-f][1,10]phenanthroline and 1,3-benzenedicarboxylate
title_fullStr A 3D mixed-valence Cu(I)/Cu(II) coordination polymer constructed by 2-(2-fluorophenyl)-1H-imidazo[4,5-f][1,10]phenanthroline and 1,3-benzenedicarboxylate
title_full_unstemmed A 3D mixed-valence Cu(I)/Cu(II) coordination polymer constructed by 2-(2-fluorophenyl)-1H-imidazo[4,5-f][1,10]phenanthroline and 1,3-benzenedicarboxylate
title_sort 3d mixed-valence cu(i)/cu(ii) coordination polymer constructed by 2-(2-fluorophenyl)-1h-imidazo[4,5-f][1,10]phenanthroline and 1,3-benzenedicarboxylate
publishDate 2015
url http://eprints.um.edu.my/16457/
_version_ 1643690280350646272
score 13.214268

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