A 3D mixed-valence Cu(I)/Cu(II) coordination polymer constructed by 2-(2-fluorophenyl)-1H-imidazo[4,5-f][1,10]phenanthroline and 1,3-benzenedicarboxylate

• Main Authors: Kong, Z.G., Guo, S.N., Sun, B., Ng, S.W.
• Format: Article
• Published: 2015
• Subjects: QD Chemistry
• Online Access: http://eprints.um.edu.my/16457/

A mixed-valence Cu(I)/Cu(II) coordination polymer, namely, [Cu-2(L)(1,3-BDC)](n) (1), has been synthesized under hydrothermal conditions (HL = 2-(2-fluorophenyl)-1H-imidazo[4,5-f][1,10]phenanthroline and 1,3-H2BDC = 1,3-benzenedicarboxylic acid). Its structure has been determined by single crystal X...