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(2-{[1,1-Bis(hydroxymethyl)-2-oxidoethyl]iminomethyl}-4-chlorophenol ato-kappa N-3,O,O `)dibutyltin(IV)

The Schiff base ligand in the title compound, [Sn(C4H9)(2)(C11H12ClNO4)], chelates to the Sn atom through the two deprotonated O atoms, as well as through the N atom, to confer an overall cis-C2SnNO2 trigonal-bipyramidal geometry at tin [C-Sn-C = 130.3 (1)degrees]. The hydroxy groups engage in O-H c...

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Main Authors: Reisi, R., Misran, M., Lo, K.M., Ng, S.W.
Format: Article
Published: International Union of Crystallography 2010
Subjects:
QC Physics
Online Access:http://eprints.um.edu.my/14772/
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spelling my.um.eprints.147722019-01-31T05:17:45Z http://eprints.um.edu.my/14772/ (2-{[1,1-Bis(hydroxymethyl)-2-oxidoethyl]iminomethyl}-4-chlorophenol ato-kappa N-3,O,O `)dibutyltin(IV) Reisi, R. Misran, M. Lo, K.M. Ng, S.W. QC Physics The Schiff base ligand in the title compound, [Sn(C4H9)(2)(C11H12ClNO4)], chelates to the Sn atom through the two deprotonated O atoms, as well as through the N atom, to confer an overall cis-C2SnNO2 trigonal-bipyramidal geometry at tin [C-Sn-C = 130.3 (1)degrees]. The hydroxy groups engage in O-H center dot center dot center dot O hydrogen bonding with the O atoms of adjacent molecules, generating a chain running along the c axis. International Union of Crystallography 2010 Article PeerReviewed Reisi, R. and Misran, M. and Lo, K.M. and Ng, S.W. (2010) (2-{[1,1-Bis(hydroxymethyl)-2-oxidoethyl]iminomethyl}-4-chlorophenol ato-kappa N-3,O,O `)dibutyltin(IV). Acta Crystallographica Section E: Structure Reports Online, 66 (4). M482-U1350. ISSN 1600-5368
institution Universiti Malaya
building UM Library
collection Institutional Repository
continent Asia
country Malaysia
content_provider Universiti Malaya
content_source UM Research Repository
url_provider http://eprints.um.edu.my/
topic QC Physics
spellingShingle QC Physics
Reisi, R.
Misran, M.
Lo, K.M.
Ng, S.W.
(2-{[1,1-Bis(hydroxymethyl)-2-oxidoethyl]iminomethyl}-4-chlorophenol ato-kappa N-3,O,O `)dibutyltin(IV)
description The Schiff base ligand in the title compound, [Sn(C4H9)(2)(C11H12ClNO4)], chelates to the Sn atom through the two deprotonated O atoms, as well as through the N atom, to confer an overall cis-C2SnNO2 trigonal-bipyramidal geometry at tin [C-Sn-C = 130.3 (1)degrees]. The hydroxy groups engage in O-H center dot center dot center dot O hydrogen bonding with the O atoms of adjacent molecules, generating a chain running along the c axis.
format Article
author Reisi, R.
Misran, M.
Lo, K.M.
Ng, S.W.
author_facet Reisi, R.
Misran, M.
Lo, K.M.
Ng, S.W.
author_sort Reisi, R.
title (2-{[1,1-Bis(hydroxymethyl)-2-oxidoethyl]iminomethyl}-4-chlorophenol ato-kappa N-3,O,O `)dibutyltin(IV)
title_short (2-{[1,1-Bis(hydroxymethyl)-2-oxidoethyl]iminomethyl}-4-chlorophenol ato-kappa N-3,O,O `)dibutyltin(IV)
title_full (2-{[1,1-Bis(hydroxymethyl)-2-oxidoethyl]iminomethyl}-4-chlorophenol ato-kappa N-3,O,O `)dibutyltin(IV)
title_fullStr (2-{[1,1-Bis(hydroxymethyl)-2-oxidoethyl]iminomethyl}-4-chlorophenol ato-kappa N-3,O,O `)dibutyltin(IV)
title_full_unstemmed (2-{[1,1-Bis(hydroxymethyl)-2-oxidoethyl]iminomethyl}-4-chlorophenol ato-kappa N-3,O,O `)dibutyltin(IV)
title_sort (2-{[1,1-bis(hydroxymethyl)-2-oxidoethyl]iminomethyl}-4-chlorophenol ato-kappa n-3,o,o `)dibutyltin(iv)
publisher International Union of Crystallography
publishDate 2010
url http://eprints.um.edu.my/14772/
_version_ 1643689896681930752
score 13.211869

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