(2-{[1,1-Bis(hydroxymethyl)-2-oxidoethyl]iminomethyl}-4-chlorophenol ato-kappa N-3,O,O `)dibutyltin(IV)
The Schiff base ligand in the title compound, [Sn(C4H9)(2)(C11H12ClNO4)], chelates to the Sn atom through the two deprotonated O atoms, as well as through the N atom, to confer an overall cis-C2SnNO2 trigonal-bipyramidal geometry at tin [C-Sn-C = 130.3 (1)degrees]. The hydroxy groups engage in O-H c...
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Main Authors: | , , , |
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Format: | Article |
Published: |
International Union of Crystallography
2010
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Subjects: | |
Online Access: | http://eprints.um.edu.my/14772/ |
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Summary: | The Schiff base ligand in the title compound, [Sn(C4H9)(2)(C11H12ClNO4)], chelates to the Sn atom through the two deprotonated O atoms, as well as through the N atom, to confer an overall cis-C2SnNO2 trigonal-bipyramidal geometry at tin [C-Sn-C = 130.3 (1)degrees]. The hydroxy groups engage in O-H center dot center dot center dot O hydrogen bonding with the O atoms of adjacent molecules, generating a chain running along the c axis. |
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