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Dichlorido[(4E,11E)-5,7,12,14-tetrabenzyl-7,14-dimethyl-1,4,8,11-tetra azacyclotetradeca-4,11-diene]cobalt(III) perchlorate

The Co(III) atom in the title complex, [CoCl(2)(C(40)H(48)N(4))]ClO(4), is octahedrally coordinated within a trans-Cl(2)N(4) donor set provided by the tetradentate macrocylic ligand and two chloride ions. The N-H atoms, which are orientated to one side of the N(4) plane, form hydrogen bonds with chl...

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Main Authors: Roy, T.G., Hazari, S.K.S., Barua, K.K., Ng, S.W., Tiekink, E.R.T.
Format: Article
Published: International Union of Crystallography 2011
Subjects:
QC Physics
Online Access:http://eprints.um.edu.my/14652/
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spelling my.um.eprints.146522019-04-16T11:38:37Z http://eprints.um.edu.my/14652/ Dichlorido[(4E,11E)-5,7,12,14-tetrabenzyl-7,14-dimethyl-1,4,8,11-tetra azacyclotetradeca-4,11-diene]cobalt(III) perchlorate Roy, T.G. Hazari, S.K.S. Barua, K.K. Ng, S.W. Tiekink, E.R.T. QC Physics The Co(III) atom in the title complex, [CoCl(2)(C(40)H(48)N(4))]ClO(4), is octahedrally coordinated within a trans-Cl(2)N(4) donor set provided by the tetradentate macrocylic ligand and two chloride ions. The N-H atoms, which are orientated to one side of the N(4) plane, form hydrogen bonds with chloride ions and perchlorate-O atoms. These along with C-H center dot center dot center dot O interactions consolidate the three-dimensional crystal structure. One of the benzene rings was disordered. This was resolved over two positions with the major component of the disorder having a site-occupancy factor of 0.672 (4). International Union of Crystallography 2011 Article PeerReviewed Roy, T.G. and Hazari, S.K.S. and Barua, K.K. and Ng, S.W. and Tiekink, E.R.T. (2011) Dichlorido[(4E,11E)-5,7,12,14-tetrabenzyl-7,14-dimethyl-1,4,8,11-tetra azacyclotetradeca-4,11-diene]cobalt(III) perchlorate. Acta Crystallographica Section E: Structure Reports Online, 67 (12). M1722-U259. ISSN 1600-5368
institution Universiti Malaya
building UM Library
collection Institutional Repository
continent Asia
country Malaysia
content_provider Universiti Malaya
content_source UM Research Repository
url_provider http://eprints.um.edu.my/
topic QC Physics
spellingShingle QC Physics
Roy, T.G.
Hazari, S.K.S.
Barua, K.K.
Ng, S.W.
Tiekink, E.R.T.
Dichlorido[(4E,11E)-5,7,12,14-tetrabenzyl-7,14-dimethyl-1,4,8,11-tetra azacyclotetradeca-4,11-diene]cobalt(III) perchlorate
description The Co(III) atom in the title complex, [CoCl(2)(C(40)H(48)N(4))]ClO(4), is octahedrally coordinated within a trans-Cl(2)N(4) donor set provided by the tetradentate macrocylic ligand and two chloride ions. The N-H atoms, which are orientated to one side of the N(4) plane, form hydrogen bonds with chloride ions and perchlorate-O atoms. These along with C-H center dot center dot center dot O interactions consolidate the three-dimensional crystal structure. One of the benzene rings was disordered. This was resolved over two positions with the major component of the disorder having a site-occupancy factor of 0.672 (4).
format Article
author Roy, T.G.
Hazari, S.K.S.
Barua, K.K.
Ng, S.W.
Tiekink, E.R.T.
author_facet Roy, T.G.
Hazari, S.K.S.
Barua, K.K.
Ng, S.W.
Tiekink, E.R.T.
author_sort Roy, T.G.
title Dichlorido[(4E,11E)-5,7,12,14-tetrabenzyl-7,14-dimethyl-1,4,8,11-tetra azacyclotetradeca-4,11-diene]cobalt(III) perchlorate
title_short Dichlorido[(4E,11E)-5,7,12,14-tetrabenzyl-7,14-dimethyl-1,4,8,11-tetra azacyclotetradeca-4,11-diene]cobalt(III) perchlorate
title_full Dichlorido[(4E,11E)-5,7,12,14-tetrabenzyl-7,14-dimethyl-1,4,8,11-tetra azacyclotetradeca-4,11-diene]cobalt(III) perchlorate
title_fullStr Dichlorido[(4E,11E)-5,7,12,14-tetrabenzyl-7,14-dimethyl-1,4,8,11-tetra azacyclotetradeca-4,11-diene]cobalt(III) perchlorate
title_full_unstemmed Dichlorido[(4E,11E)-5,7,12,14-tetrabenzyl-7,14-dimethyl-1,4,8,11-tetra azacyclotetradeca-4,11-diene]cobalt(III) perchlorate
title_sort dichlorido[(4e,11e)-5,7,12,14-tetrabenzyl-7,14-dimethyl-1,4,8,11-tetra azacyclotetradeca-4,11-diene]cobalt(iii) perchlorate
publisher International Union of Crystallography
publishDate 2011
url http://eprints.um.edu.my/14652/
_version_ 1643689868174295040
score 13.188404

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