2,2 `-[p-Phenylenebis(methylideneazanediyl)]dipyridinium bis(hydrogensulfate) dihydrate
The cation of the title salt, C18H20N42+center dot 2HSO(4)(-)center dot 2H(2)O, lies on a center of inversion with the mid-point directly in the middle of the p-phenylene ring. Within the hydrogensulfate ion, the S-O(H) bond is the longest of the S-O bonds. The dihedral angle between the central and...
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my.um.eprints.117032019-01-31T04:08:53Z http://eprints.um.edu.my/11703/ 2,2 `-[p-Phenylenebis(methylideneazanediyl)]dipyridinium bis(hydrogensulfate) dihydrate Gao, S. Qi, Xiao-Juan Kong, Li-Li Ng, S.W. Q Science (General) The cation of the title salt, C18H20N42+center dot 2HSO(4)(-)center dot 2H(2)O, lies on a center of inversion with the mid-point directly in the middle of the p-phenylene ring. Within the hydrogensulfate ion, the S-O(H) bond is the longest of the S-O bonds. The dihedral angle between the central and terminal ring of the cation is 78.6 (2)degrees. In the crystal, the cation, anion and water molecule interact by O-H center dot center dot center dot O and N-H center dot center dot center dot O hydrogen bonds, generating a three-dimensional network. International Union of Crystallography 2010 Article PeerReviewed Gao, S. and Qi, Xiao-Juan and Kong, Li-Li and Ng, S.W. (2010) 2,2 `-[p-Phenylenebis(methylideneazanediyl)]dipyridinium bis(hydrogensulfate) dihydrate. Acta Crystallographica Section E: Structure Reports Online, 66 (12). O3300-U1823. ISSN 1600-5368 |
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Q Science (General) Gao, S. Qi, Xiao-Juan Kong, Li-Li Ng, S.W. 2,2 `-[p-Phenylenebis(methylideneazanediyl)]dipyridinium bis(hydrogensulfate) dihydrate |
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The cation of the title salt, C18H20N42+center dot 2HSO(4)(-)center dot 2H(2)O, lies on a center of inversion with the mid-point directly in the middle of the p-phenylene ring. Within the hydrogensulfate ion, the S-O(H) bond is the longest of the S-O bonds. The dihedral angle between the central and terminal ring of the cation is 78.6 (2)degrees. In the crystal, the cation, anion and water molecule interact by O-H center dot center dot center dot O and N-H center dot center dot center dot O hydrogen bonds, generating a three-dimensional network. |
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Article |
author |
Gao, S. Qi, Xiao-Juan Kong, Li-Li Ng, S.W. |
author_facet |
Gao, S. Qi, Xiao-Juan Kong, Li-Li Ng, S.W. |
author_sort |
Gao, S. |
title |
2,2 `-[p-Phenylenebis(methylideneazanediyl)]dipyridinium bis(hydrogensulfate) dihydrate |
title_short |
2,2 `-[p-Phenylenebis(methylideneazanediyl)]dipyridinium bis(hydrogensulfate) dihydrate |
title_full |
2,2 `-[p-Phenylenebis(methylideneazanediyl)]dipyridinium bis(hydrogensulfate) dihydrate |
title_fullStr |
2,2 `-[p-Phenylenebis(methylideneazanediyl)]dipyridinium bis(hydrogensulfate) dihydrate |
title_full_unstemmed |
2,2 `-[p-Phenylenebis(methylideneazanediyl)]dipyridinium bis(hydrogensulfate) dihydrate |
title_sort |
2,2 `-[p-phenylenebis(methylideneazanediyl)]dipyridinium bis(hydrogensulfate) dihydrate |
publisher |
International Union of Crystallography |
publishDate |
2010 |
url |
http://eprints.um.edu.my/11703/ |
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1643689120081379328 |
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13.211869 |