2,2 `-[p-Phenylenebis(methylideneazanediyl)]dipyridinium bis(hydrogensulfate) dihydrate
The cation of the title salt, C18H20N42+center dot 2HSO(4)(-)center dot 2H(2)O, lies on a center of inversion with the mid-point directly in the middle of the p-phenylene ring. Within the hydrogensulfate ion, the S-O(H) bond is the longest of the S-O bonds. The dihedral angle between the central and...
Saved in:
Main Authors: | , , , |
---|---|
Format: | Article |
Published: |
International Union of Crystallography
2010
|
Subjects: | |
Online Access: | http://eprints.um.edu.my/11703/ |
Tags: |
Add Tag
No Tags, Be the first to tag this record!
|
Summary: | The cation of the title salt, C18H20N42+center dot 2HSO(4)(-)center dot 2H(2)O, lies on a center of inversion with the mid-point directly in the middle of the p-phenylene ring. Within the hydrogensulfate ion, the S-O(H) bond is the longest of the S-O bonds. The dihedral angle between the central and terminal ring of the cation is 78.6 (2)degrees. In the crystal, the cation, anion and water molecule interact by O-H center dot center dot center dot O and N-H center dot center dot center dot O hydrogen bonds, generating a three-dimensional network. |
---|