Crystal structures and Hirshfeld surface analyses of (N-hexyl-N-methyldithiocarbamato-κ2 S,S′)triphenyltin(IV) and [N-methyl-N-(2-phenylethyl)dithiocarbamato-κ2 S,S′]triphenyltin(IV)

• Main Authors: Rapidah Mohamad,, Normah Awang,, Nurul Farahana Kamaludin,, Jotani, Mukesh M., Tiekink, Edward R. T. *
• Format: Article
• Language: English
• Published: International Union of Crystallography 2018
• Subjects: QD Chemistry
• Online Access: http://eprints.sunway.edu.my/797/1/Tiekink%20E%20Crystal%20structures%20Acta%20Cryst%20E74%20630_.pdf; http://eprints.sunway.edu.my/797/; http://doi.org/10.1107/S2056989018005133

The crystal and molecular structures of two triphenyltin dithiocarbamate compounds, viz. [Sn(C6H5)3(C8H16NS2)], (I), and [Sn(C6H5)3(C10H12NS2)], (II), are described. The dithiocarbamate ligand in each molecule coordinates in an asymmetric fashion resulting in heavily distorted tetrahedral C3S coordi...